<rdf:RDF xmlns:rdf="http://www.w3.org/1999/02/22-rdf-syntax-ns#" xmlns:dcterms="http://purl.org/dc/terms/">
<rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/2772">
    <dcterms:title><![CDATA[<strong>Systematic Coupled Cluster, Brueckner Coupled Cluster, G3, CBS-QB3, and DFT Investigation of SX Diatomics; X ) First- or Second-Row Atom.</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[QUIMICA FISICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2004]]></dcterms:subject>
    <dcterms:abstract><![CDATA[The SX diatomics, X = first- or second-row atom, have been studied employing coupled cluster theory and the aug-cc-pV(X+d)Z basis sets. To estimate &Delta;fH&deg;298, we have included a correction for core&minus;valence (CV) correlation, spin&minus;orbit splitting, and scalar-relativistic (SR) effects. For SO and SC, the estimated &Delta;fH&deg;298 values are 0.5 kcal/mol within the experiment. However, for the remaining molecules, a revision of their &Delta;H&deg;f,298 are required. Deviations as large as 10 kcal/mol have been found between our best estimates and the values adopted by the NIST-JANAF tables. The proposed &Delta;fH&deg;298 (&plusmn;0.5kcal/mol) are 67.6 (SB), 66.7 (SN), 0.8 (SF), 47.4 (SAl), 27.9 (SSi), 38.1 (SP), 29.4 (S2), and 27.1 (SCl) kcal/mol. For comparative purposes we performed BD(T), G3, CBS-QB3, B3LYP, and B3PW91 calculations. The mean absolute error (MAE) of the G3 and CBS-QB3 &Delta;fH&deg;298 with respect to our best results is 1.0 kcal/mol for both methodologies, whereas for B3LYP/6-311+G(3df) and B3PW91/6-311+G(3df), the MAE is 1.6 and 2.0 kcal/mol, respectively. At the coupled cluster level of theory, with respect to the experiment, the MAE of the equilibrium bond lengths is 0.0013 and 0.0012 &Aring; for the first- and second-row SX, respectively. This result involves extrapolation to the CBS limit, a correction for CV and SR effects, and also a correction for complete triple excitations. Two molecules presented an unstable HF wave function, SN and SP. In both cases, the use of the CCSDT and BD(T) methods outperformed CCSD(T). Our spin&minus;orbit corrected coupled cluster adiabatic electron affinities (EAad) are &plusmn;0.7 kcal/mol within the experiment for SN, SO, SF, and S2. However, some discrepancies were found for SC and SAl. Our best estimates are EAad(SC) = 2.3 kcal/mol and EAad(SAl) = 62.5 kcal/mol, 2.4 and 1.6 kcal/mol larger than the experimental EAad, respectively. For SB, SSi, SP, and SCl, we propose new EAad of 53.7, 12.4, 36.5, and 59.0 kcal/mol, respectively. The MAE of the CBS-QB3 and G3 EAad with respect to our estimated EAad is 0.9 kcal/mol for both methodologies, whereas for B3LYP/6-311+G(3df) and B3PW91/6-311+G(3df), the MAE are 1.9 and 2.7 kcal/mol, respectively, but 50% of the error is provided only by SC and SN. Systematic Coupled Cluster, Brueckner Coupled Cluster, G3, CBS-QB3, and DFT Investigation of SX Diatomics; X = First- or Second-Row Atom - ResearchGate. Available from: http://www.researchgate.net/publication/231639185_Systematic_Coupled_Cluster_Brueckner_Coupled_Cluster_G3_CBS-QB3_and_DFT_Investigation_of_SX_Diatomics_X__First-_or_Second-Row_Atom [accessed Apr 16, 2015].]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<a title="Curriculum" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=330eeda61de9937431a7182c44a5ee24"><strong>Denis, Pablo A</strong></a>]]></dcterms:creator>
    <dcterms:source><![CDATA[Journal of Physical Chemistry v. 108, 2004. -- p. 11092-11100]]></dcterms:source>
    <dcterms:publisher><![CDATA[American Chemical Society]]></dcterms:publisher>
    <dcterms:date><![CDATA[2004]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes</p>
<p>(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA</strong> - La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>
<p>&nbsp;</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[DOI: 10.1021/jp047834e]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/1845">
    <dcterms:title><![CDATA[<strong>Systemic and presystemic of carbamazepine to carbamazepine-10,11-Epoxide during long term treatment</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[CARBAMAZEPINA]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIODISPONIBILIDAD]]></dcterms:subject>
    <dcterms:subject><![CDATA[2006]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAF&Iacute;A NACIONAL QU&Iacute;MICA]]></dcterms:subject>
    <dcterms:creator><![CDATA[<a title="Curr&iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=caabbc98478c9c9fb71e4b0eb4e4ccd5" target="_blank"><strong>Fagiolino, Pietro</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>V&aacute;zquez, M.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Olano, I.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Delfino, A.</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[Journal of Epilepsy and Clinical Neurophysiology v. 12, no. 1, 2006. -- p. 13-16]]></dcterms:source>
    <dcterms:publisher><![CDATA[Liga Brasileira de Epilepsia (LBE)]]></dcterms:publisher>
    <dcterms:date><![CDATA[2006]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong><br /> <br /> (Por favor lea este aviso antes de abrir los documentos u objetos)<br /> <br /> <strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes<br /> <br /> (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)<br /> <br /> <strong>ADVERTENCIA -</strong> La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[ISSN 1676-2649]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/6447">
    <dcterms:title><![CDATA[<strong>T- and pH-Dependent Kinetics of the Reactions of &middot;OH(aq) with Glutaric and Adipic Acid for Atmospheric Aqueous-Phase Chemistry</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[ACIDO ADIPICO]]></dcterms:subject>
    <dcterms:subject><![CDATA[ACIDO GLUTARICO]]></dcterms:subject>
    <dcterms:subject><![CDATA[DFT]]></dcterms:subject>
    <dcterms:subject><![CDATA[CINETICA DE COMPETENCIA]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2021]]></dcterms:subject>
    <dcterms:abstract><![CDATA[<p>Glutaric acid and adipic acid are dicarboxylic acids (DCAs) that are commonly found in atmospheric aerosols and cloud droplets. Within this study, the temperature- and pH-dependent rate constants of aqueous-phase OH radical reactions<br />of these two DCAs were determined through the competition kinetics method. The following Arrhenius expressions were derived for the temperature dependency of the OH radical reaction with glutaric acid: k(T, H2A) = (3.9 &plusmn; 0.1) &times; 1010 &times; exp[(&minus;1270 &plusmn; 200 K)/T], k(T, HA&minus;) = (2.3 &plusmn; 0.1) &times; 1011 &times; exp[(&minus;1660 &plusmn; 190 K)/T], k(T, A2&minus;) = (1.4 &plusmn; 0.1) &times; 1011 &times; exp[(&minus;1400 &plusmn; 170 K)/T]. Similarly, for adipic acid: k(T, H2A)<br />= (7.5 &plusmn; 0.2) &times; 1010 &times; exp[(&minus;1210 &plusmn; 170 K)/T], k(T, HA&minus;) = (9.5 &plusmn; 0.3) &times; 1010 &times; exp[(&minus;1200 &plusmn; 200 K)/T], k(T, A2&minus;) = (8.7 &plusmn; 0.2) &times; 1010 &times; exp[(&minus;1100 &plusmn; 170 K)/T] (in units of L mol&minus;1 s&minus;1). Density functional theory (DFT) calculations were performed to calculate the energy barrier of the H atom abstraction. The calculation results show that the energy barriers at the C&beta;-atoms of the two DCAs are much lower than those at the C&alpha;-atoms, indicating that the H atom abstractions predominantly occur at the C&beta;-atoms. The increased &middot;OH rate constant in the case of the deprotonated form can be explained by the reduction of energy barrier, which is predominately caused by the variation of the inductive effect of the carboxyl group. As an important sink in the atmosphere, the degradation of glutaric acid and adipic acid by &middot;OH under atmospheric conditions can be accurately described by the Arrhenius expressions obtained.</p>]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Wen, Liang</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Schaefer, Thomas</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>He, Lin</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Zhang, Yimu</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Sun, Xiaomin</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://exportcvuy.anii.org.uy/cv/?a7868d1a46654e7a04ba7167141502086fa0cfad8b13463f75d90af715685994bc8f3eafaad6f6d2f6647277c9782143df93695c8a7d8e14295323ca2e2847d3" target="_blank"><strong>Ventura, Oscar N.</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Herrmann, Hartmut</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[ACS Earth and Space Chemistry,&nbsp;v. 5, n&deg; 8, 2021. -- pp. 1854-1864.]]></dcterms:source>
    <dcterms:publisher><![CDATA[ACS Publications]]></dcterms:publisher>
    <dcterms:date><![CDATA[2021]]></dcterms:date>
    <dcterms:rights><![CDATA[<p dir="ltr"><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p dir="ltr"><span>(Por favor lea este aviso antes de abrir los documentos u objetos)</span></p>
<p dir="ltr"><strong>La legislaci&oacute;n uruguaya protege el derechode autor</strong><span>&nbsp;sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</span></p>
<span id="docs-internal-guid-9d2103f7-7fff-c813-00c7-2528fd4891ff"><strong>ADVERTENCIA:</strong><span>&nbsp;La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</span></span>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[<p align="JUSTIFY"><span style="color: #000000;"><span style="font-family: Arial, sans-serif;"><span style="font-size: small;"><span>10.1021/acsearthspacechem.1c00163</span></span></span></span></p>]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5601">
    <dcterms:title><![CDATA[<strong>T&eacute;cnias anal&iacute;ticas de ketoprofeno materia prima, comprimidos, gel, supositorios e injectables</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>KETOPROFENO</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>QUIMICA ANALITICA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>MATERIA PRIMA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>FORMAS GALENICAS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>COMPRIMIDOS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>GEL</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>SUPOSITORIOS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>INYECCIONES (MEDICAMENTOS)</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1998]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1983-1998]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5160">
    <dcterms:title><![CDATA[<strong>T&eacute;cnias anal&iacute;ticas para la determinaci&oacute;n de tiamina (vitamina B1) en preparaciones farmac&eacute;uticas (en preparados multivitam&iacute;nicos)</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>QUIMICA ANALITICA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>TIAMINA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>VITAMINA B1</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>PRODUCTOS FARMACEUTICOS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>PREPARADOS MULTIVITAMINICOS</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1984]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1973-1981]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5614">
    <dcterms:title><![CDATA[<strong>T&eacute;cnica anal&iacute;tica de residuos del pesticida Quinclorac; 8-quinolinecarboxylic acid, 3,7,-dichloro; 3,7-dichloro-8-quinolinecarbocylic acid; CAS number: 84087-01-4</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>QUINCLORAC</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>HERBICIDAS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>RESIDUOS DE PLAGUICIDAS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>QUIMICA ANALITICA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>PRODUCTOS AGRICOLAS</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1998]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1992-1996]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/2552">
    <dcterms:title><![CDATA[<strong>T&eacute;cnica para la separaci&oacute;n y el reconocimiento del grupo 3 de cationes (Fe+++, Al+++, Cr+++) incluyendo los iones frecuentes Zn++++, Ti++++, UO2++++, y Ce++++</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[QUIMICA FISICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[1962]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAF&Iacute;A NACIONAL QU&Iacute;MICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[CATIONES]]></dcterms:subject>
    <dcterms:creator><![CDATA[<strong>Lema, J. D.</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[COR : Comunicaciones Originales Cortas y Res&uacute;menes v.1, n&ordm;. 2, 1962. -- p. 114-115 com. 74]]></dcterms:source>
    <dcterms:publisher><![CDATA[Asociaci&oacute;n de Estudiantes de Qu&iacute;mica (Uruguay)]]></dcterms:publisher>
    <dcterms:date><![CDATA[1962]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya protege el derecho de autor</strong> sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA -</strong> La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Espa&ntilde;ol]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/2493">
    <dcterms:title><![CDATA[<strong>T&eacute;cnica r&aacute;pida para la obtenci&oacute;n de ferrato (VI) de potasio</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[QUIMICA ANALITICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[FERRATO DE POTASIO]]></dcterms:subject>
    <dcterms:subject><![CDATA[1962]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAF&Iacute;A NACIONAL QU&Iacute;MICA]]></dcterms:subject>
    <dcterms:creator><![CDATA[<strong>Servian, J. L.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Martres, R. W.</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[COR : Comunicaciones Originales Cortas y Res&uacute;menes v. 1, n&ordm;. 1, 1962. -- p. 19 com. 15]]></dcterms:source>
    <dcterms:publisher><![CDATA[Asociaci&oacute;n de Estudiantes de Qu&iacute;mica (Uruguay)]]></dcterms:publisher>
    <dcterms:date><![CDATA[1962]]></dcterms:date>
    <dcterms:rights><![CDATA[<p class="western" lang="es-ES" align="left"><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p class="western" lang="es-ES">(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p class="western" lang="es-ES"><strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes</p>
<p class="western" lang="es-ES">(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p class="western" style="margin-bottom: 0cm;" lang="es-ES"><strong>ADVERTENCIA</strong> - La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Espa&ntilde;ol]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/605">
    <dcterms:title><![CDATA[<strong>T&eacute;cnica simplificada para la determinaci&oacute;n de glucosa en la orina de los diab&eacute;ticos</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[1958]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAF&Iacute;A NACIONAL QU&Iacute;MICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[DIABETES]]></dcterms:subject>
    <dcterms:subject><![CDATA[ORINA]]></dcterms:subject>
    <dcterms:subject><![CDATA[<p class="western" style="margin-bottom: 0cm; line-height: 100%;" lang="pt-BR" align="justify">M&Eacute;TODO DE FEHLING-CAUSSE-BONNANS</p>]]></dcterms:subject>
    <dcterms:subject><![CDATA[GLUCOSA]]></dcterms:subject>
    <dcterms:abstract><![CDATA[En el n&uacute;mero 1-3 (vol. V) a&ntilde;o 1955, p&aacute;gina 42D de esta Revista "pR", publiqu&eacute; una t&eacute;cnica similar. La t&eacute;cnica que ahora propongo es igualmente una adaptaci&oacute;n del m&eacute;todo Causse y Bonnans y ha sido simplificada para facilitar su empleo, aunque algo menos precisa que la anterior se adapta bien al control cl&iacute;nico del diab&eacute;tico.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Saredo, Juan F.</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[pR : &Oacute;rgano Oficial de la Asociaci&oacute;n de Estudiantes de Qu&iacute;mica (Uruguay) v. 8, 1958. -- p.45-50]]></dcterms:source>
    <dcterms:publisher><![CDATA[Asociaci&oacute;n de Estudiantes de Qu&iacute;mica (Uruguay)]]></dcterms:publisher>
    <dcterms:date><![CDATA[1958]]></dcterms:date>
    <dcterms:rights><![CDATA[<strong>Informaci&oacute;n sobre Derechos de Autor</strong><br /><br />(Por favor lea este aviso antes de abrir los documentos u objetos)<br /><br /><strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes<br /><br />(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)<br /><br /><strong>ADVERTENCIA -</strong> La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.]]></dcterms:rights>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Espa&ntilde;ol]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5633">
    <dcterms:title><![CDATA[<strong>T&eacute;cnicas anal&iacute;ticas de orfenadrina + paracetamol en comprimidos</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>ORFENADRINA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>PARACETAMOL</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>COMPRIMIDOS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>QUIMICA ANALITICA</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1998]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1987-1991]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5729">
    <dcterms:title><![CDATA[<strong>T&eacute;cnicas anal&iacute;ticas para determinaci&oacute;n de loratadina en forma farmac&eacute;utica s&oacute;lida para administraci&oacute;n oral</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>LORATADINA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>QUIMICA ANALITICA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>FORMAS GALENICAS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>SOLIDOS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>ADMINISTRACION POR VIA ORAL</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1999]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1994-1998]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5638">
    <dcterms:title><![CDATA[<strong>T&eacute;cnicas anal&iacute;ticas para la determinaci&oacute;n de diclofenac en materia prima</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>DICLOFENAC</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>MATERIA PRIMA</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>QUIMICA ANALITICA</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1998]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1990-1997]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/1153">
    <dcterms:title><![CDATA[<strong>T&eacute;cnicas de dosificaci&oacute;n del colesterol total del suero</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[URUGUAY]]></dcterms:subject>
    <dcterms:subject><![CDATA[ANALISIS CLINICOS]]></dcterms:subject>
    <dcterms:subject><![CDATA[COLESTEROL]]></dcterms:subject>
    <dcterms:subject><![CDATA[QUIMICA ORGANICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[MONOGRAFIA TECNICA]]></dcterms:subject>
    <dcterms:creator><![CDATA[<strong>Laiolo, Mario C</strong>]]></dcterms:creator>
    <dcterms:publisher><![CDATA[Montevideo : UdelaR-Facultad de Química]]></dcterms:publisher>
    <dcterms:date><![CDATA[1977 p.]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong><em>Informaci&oacute;n sobre Derechos de Autor</em></strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><em><strong>La legislaci&oacute;n uruguaya protege el derecho</strong></em> de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA -</strong> La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:extent><![CDATA[133 p.]]></dcterms:extent>
    <dcterms:language><![CDATA[Espa&ntilde;ol]]></dcterms:language>
    <dcterms:type><![CDATA[Monograf&iacute;as]]></dcterms:type>
    <dcterms:identifier><![CDATA[MT 616-074 LAI]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/6482">
    <dcterms:title><![CDATA[<strong>T908 Polymeric Micelles Improved the Uptake of Sgc8-c Aptamer Probe in Tumor-Bearing Mice: A Co-Association Study between the Probe and Preformed Nanostructures</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<p>MICELAS POLIMERICAS</p>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<p>APTAMERO SGC8-C</p>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<p>ORIENTACION ACTIVA</p>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<p>SONDAS</p>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<p>TUMOR</p>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<p>BIBLIOGRAFIA NACIONAL QUIMICA</p>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<p>2022</p>]]></dcterms:subject>
    <dcterms:abstract><![CDATA[Aptamers are oligonucleotides that have the characteristic of recognizing a target with high affinity and specificity. Based on our previous studies, the aptamer probe Sgc8-c-Alexa647 is a promising tool for molecular imaging of PTK7, which is an interesting biomarker in cancer. In order to improve the delivery of this probe as well as create a novel drug delivery nanosystem targeted to the PTK7 receptor, we evaluate the co-association between the probe and preformed nanostructures. In this work, preformed pegylated liposomes (PPL) and linear and branched pristine polymeric micelles (PMs), based on PEO&ndash;PPO&ndash;PEO triblock copolymers were used: poloxamer F127&reg; and poloxamines T1307&reg; and T908&reg;. For it, Sgc8-c-Alexa647 and its co-association with the different nanostructures was exhaustively analyzed. DLS analysis showed nanometric sizes, and TEM and AFM showed notable differences between free- and co-associated probe. Likewise, all nanosystems were evaluated on A20 lymphoma cell line overexpressing PTK7, and the confocal microscopy images showed distinctness in cellular uptake. Finally, the biodistribution in BALB/c mice bearing lymphoma-tumor and pharmacokinetic study revealed an encouraging profile for T908-probe. All data obtained from this work suggested that PMs and, more specifically T908 ones, are good candidates to improve the pharmacokinetics and the tumor uptake of aptamer-based probes.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Castelli, Romina</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Ibarra, Manuel</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Faccio,&nbsp;Ricardo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Miraballes,&nbsp;Iris</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Fern&aacute;ndez,&nbsp;Marcelo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Moglioni,&nbsp;Albertina</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Cabral,&nbsp;Pablo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Cerecetto,&nbsp;Hugo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Glisoni,&nbsp;Romina J.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Calzada,&nbsp;Victoria</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[Pharmaceuticals, v.15, n&deg;15, 2022. --]]></dcterms:source>
    <dcterms:publisher><![CDATA[MDPI]]></dcterms:publisher>
    <dcterms:date><![CDATA[2022]]></dcterms:date>
    <dcterms:rights><![CDATA[<p dir="ltr"><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p dir="ltr">(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p dir="ltr"><strong>La legislaci&oacute;n uruguaya protege el derecho de autor</strong>&nbsp;sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<span id="docs-internal-guid-9d2103f7-7fff-c813-00c7-2528fd4891ff"><strong>ADVERTENCIA:</strong>&nbsp;La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</span>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[10.3390/ph15010015]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5725">
    <dcterms:title><![CDATA[<strong>Tablas de informaci&oacute;n sobre fuel oil</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>COMBUSTIBLES LIQUIDOS</strong>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<strong>DATOS</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1999]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:language><![CDATA[Espa&ntilde;ol]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1999]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/113">
    <dcterms:title><![CDATA[<strong>Tailoring chain length selectivity of a solvent-tolerant lipase activity from Aspergillus niger MYA 135 by submerged fermentation</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[ENZIMAS]]></dcterms:subject>
    <dcterms:subject><![CDATA[LIPASAS]]></dcterms:subject>
    <dcterms:subject><![CDATA[ASPERGILLUS NIGER]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2012]]></dcterms:subject>
    <dcterms:abstract><![CDATA[<p>The use of biocatalysts in fuel industry is an interesting and greener alternative. In this connection, it was found<br />that the chain-length selectivity profile of a solvent-tolerant lipase activity fromAspergillus nigerMYA 135 determined<br />in both hydrolytic and synthetic reactions depended on theway that the enzymewas prepared. Indeed, a<br />mycelium-bound (Mb) lipase activity obtained either in presence or absence of 2% olive oil as well as a lyophilized<br />supernatant extract obtained in presence of 2% olive oil showed different specificity constants (1/&alpha;).<br />Thus, the highest substrate specificity in hydrolysis reaction was observed toward a long-chain fatty acid (C18;<br />1/&alpha;=1.0) with the constitutive Mb-lipase in organic medium. In addition, this lipase preparation was specific<br />toward the synthesis of methyl palmitate during esterification (1/&alpha;=1.00) and ethyl palmitate in transesterification<br />(1/&alpha;=0.93). Interestingly, the induced Mb-lipase was a highly reactive biocatalyst preparation in both<br />transesterification (58% of the reactions displayed 1/&alpha;&gt;0.5) and esterification (88% of the reactions displayed<br />1/&alpha;&gt;0.7) reactions. On the contrary, the induced lyophilized supernatant was the most specific enzymatic<br />system showing a clear preference for linoleic acid in esterification reactions (1/&alpha; around of 0.77 for all acyl<br />acceptors tested).</p>]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Romero, Cintia M.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Pera, L. M.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Olivaro, Cristina</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a title="Curriculum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=d8a37bd83eccca2cc36974bdf1606cb7" target="_blank"><strong>V&aacute;zquez, Alvaro</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Baigori, Mario D.</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[Fuel Processing Technology v. 98, no. 4, 2012. -- p. 223-29]]></dcterms:source>
    <dcterms:publisher><![CDATA[Elsevier]]></dcterms:publisher>
    <dcterms:date><![CDATA[2012]]></dcterms:date>
    <dcterms:rights><![CDATA[<p align="LEFT"><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes</p>
<p>(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p style="margin-bottom: 0cm;"><strong>ADVERTENCIA</strong> - La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>
<p><br /><br /></p>
<p style="margin-bottom: 0cm;">&nbsp;</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[doi:10.1016/j.fuproc.2012.01.020]]></dcterms:identifier>
    <dcterms:coverage><![CDATA[<p>&nbsp;</p>
<p>&nbsp;</p>]]></dcterms:coverage>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/1524">
    <dcterms:title><![CDATA[<strong>Tailoring mixed-valence CoIII/FeII complexes for their potential use as sensitizers in dye sensitized solar cells</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[COBRE]]></dcterms:subject>
    <dcterms:subject><![CDATA[HIERRO]]></dcterms:subject>
    <dcterms:subject><![CDATA[COMPLEJOS]]></dcterms:subject>
    <dcterms:subject><![CDATA[2008]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:abstract><![CDATA[Dinuclear class II CoIII/FeII mixed-valence complexes of type [LnCoIII(m-NC)FeII(CN)3L2]m (where Ln represents a pentadentate macrocycle and L2 a bpy ligand or two cyanides) have electronic properties that make them possible sensitizers in DSSC (dye sensitized solar cells). For this purpose the new complex Na2[{trans-L14COOCoIII(m-NC)}FeII(CN)5] has been prepared and characterized by the usual methods and its sensitizer properties compared with those of the already known [{trans-L15CoIII(m-NC)}FeII(CN)3(bipy)eq,ax](ClO4). The complex [{trans- L14COOCoIII(m-NC)}FeII(CN)5]2 has been designed for the actuation of an electron injection from the cobalt centre on MMCT, while the [{trans-LnCoIII(m-NC)}FeII(CN)3(bipy)]+ structure can produce a tuned injection from the iron centre via an MLCT electronic state, as described for similar systems. The characterization on solid oxide semiconductor supports has been carried out for these two complexes and the results have been compared with the behaviour observed in aqueous solution and in solvents of varying polarities. Their use in DSSC has been checked and, while a sensitizer response is observed for [{trans-L14COOCoIII(m-NC)}FeII(CN)5]2, complex [{trans-L15CoIII(m-NC)}FeII(CN)3(bipy)eq,ax]+ does not produce any electrical current on illumination. The low efficiency of the built DSSC can be easily related both with the very low value of the extinction coefficient of the MMCT band responsible for the electron injection, and with the small driving force for the reduction of the complex with the standard I2/I3 system used after electron injection.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Bernhardt, Paul V.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Boschloo, Gerrit K.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Bozoglian, Fernando</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Hagfeldt, Anders</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Mart&iacute;nez, Manuel</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[New Journal of Chemistry v. 32, no. 4, 2008. -- p. 705-711]]></dcterms:source>
    <dcterms:publisher><![CDATA[Royal Society of Chemistry]]></dcterms:publisher>
    <dcterms:date><![CDATA[2008]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes</p>
<p>(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA</strong> - La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[DOI: 10.1039/b716855a]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/5742">
    <dcterms:title><![CDATA[<strong>Tamsulosin</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<strong>TAMSULOSINA</strong>]]></dcterms:subject>
    <dcterms:publisher><![CDATA[Biblioteca-FQ]]></dcterms:publisher>
    <dcterms:date><![CDATA[1999]]></dcterms:date>
    <dcterms:format><![CDATA[Papel]]></dcterms:format>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Bibliograf&iacute;a]]></dcterms:type>
    <dcterms:temporal><![CDATA[1996-1998]]></dcterms:temporal>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/22">
    <dcterms:title><![CDATA[<strong>Tandem repeat-tRNA (TRtRNA) PCR method for the molecular typing of non-Saccharomyces subspecies</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[VINOS]]></dcterms:subject>
    <dcterms:subject><![CDATA[LEVADURAS]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2012]]></dcterms:subject>
    <dcterms:abstract><![CDATA[There is a worldwide trend to understand the impact of non-Saccharomyces yeast species on the process of winemaking. Although the predominant species at the end of the fermentation is Saccharomyces cerevisiae, several non-Saccharomyces species present during the first days of the process can produce and/or release aromas that improve the bouquet and complexity of the final wine. Since no genomic sequences are available for the predominant non-Saccharomyces species selected from grapes or musts (Hanseniaspora uvarum, Hanseniaspora vineae, Hanseniaspora opuntiae, Metschnikowia pulcherrima, Candida zemplinina), a reproducible PCR method was devised to discriminate strains at the subspecies level. The method combines different oligonucleotides based on tandem repeats with a second oligonucleotide based on a conserved tRNA region, specific for ascomycetes. Tandem repeats are randomly dispersed in all eukaryotic genomes and tRNA genes are conserved and present in several copies in different chromosomes. As an example, the method was applied to discriminate native M. pulcherrima strains but it could be extended to differentiate strains from other non-Saccharomyces species. The biodiversity of species and strains found in the grape ecosystem is a potential source of new enzymes, fungicides and/or novel sustainable methods for biological control of phytopathogens.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Barquet, Marianne</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Mart&iacute;n Valverde, Antonio</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Medina, Karina</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Perez, Gabriel</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=e2bbd8e658a30ffb5ed00147ebed8a1a"><strong>Carrau, Francisco</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Gaggero de Munno, Carina</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[Applied Microbiology and Biotechnology&nbsp; v. 93, no. 2, 2012. -- p. 807-814]]></dcterms:source>
    <dcterms:publisher><![CDATA[Springer]]></dcterms:publisher>
    <dcterms:date><![CDATA[2012]]></dcterms:date>
    <dcterms:rights><![CDATA[<p align="LEFT"><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes</p>
<p>(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p style="margin-bottom: 0cm;"><strong>ADVERTENCIA</strong> - La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Inglés]]></dcterms:language>
    <dcterms:type><![CDATA[Artículo]]></dcterms:type>
    <dcterms:identifier><![CDATA[ISSN 0175-7598]]></dcterms:identifier>
    <dcterms:identifier><![CDATA[DOI 10.1007/s00253-011-3714-4]]></dcterms:identifier>
    <dcterms:coverage><![CDATA[<p>&nbsp;</p>
<p>&nbsp;</p>]]></dcterms:coverage>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/6705">
    <dcterms:title><![CDATA[<strong>Tannat grape pomace as an ingredient for potential functional biscuits : bioactive compound identification, in vitro bioactivity, food safety, and sensory evaluation</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[COMPUESTOS BIOACTIVOS]]></dcterms:subject>
    <dcterms:subject><![CDATA[SEGURIDAD ALIMENTARIA]]></dcterms:subject>
    <dcterms:subject><![CDATA[ANALISIS SENSORIAL]]></dcterms:subject>
    <dcterms:subject><![CDATA[ORUJO DE UVA]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2023]]></dcterms:subject>
    <dcterms:abstract><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya protege el derecho</strong>&nbsp;de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA -</strong>&nbsp;La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?5935ded904d63ca6befc8586f8cc121d" target="_blank"><strong>Olt, Victoria</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?65ae80767e3d44791a1f7bed8d0842d1c9595207208795fa0f294e6a3d658745260932331e8bc8554f97f35689f8721cbcb094945d3e6d67042d98ea5e3494b7" target="_blank"><strong>B&aacute;ez, Jessica</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?ce93ce62dc0559af8b8f9f5243ab3d0a" target="_blank"><strong>Curbelo, Romina</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?e1ba7de0d572172f427d637a61cf7ffedcaca3f4642b955065a2f3a72fb70a03516776171609b3227f51a8c2647cd41dcfe25b5f501e985b684341e0de901a45" target="_blank"><strong>Boido, Eduardo</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?b8110dcaf036ffc0dae30a2f60d464cb11603012429fac16300f3e0c79bc76d1e596cc9d53f8915f46ffa7e578d979292e34c20df05ff6344fe237694a004603" target="_blank"><strong>Amarillo, Miguel</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cvsni/?urlId=9e0226832c58b76dfe35556298c9ffe5965c331085e652b1ea024ab73ead6296bf151c5e3e17d95e2ba698422846702e67f3356835059c00f94c1edcd55e4f85&amp;convocatoria=21&amp;formato=html" target="_blank"><strong>G&aacute;mbaro, Adriana</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?5b9c9936b20b7b2352e3813baf42a29613b5a147258df4cae843cd087fc76b2042c0e3be63baf8ed05b5d15613f8d17a3bececa370048a98b8d741075138e04f" target="_blank"><strong>Albor&eacute;s, Silvana</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?00b33df8024fc67255044b617fb39573f6662628ebe84b9377474d0df1d9615d9d104c46f2ccbe946d4c8fa60fa2bb29a14429abf31dcba401f3de274ead25d3" target="_blank"><strong>Gerez Garc&iacute;a, Natalia</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?833da37ef6f0f9787a1257ffd7f129a8a148e2bddb9022c6569913519dd3e78a15f65da0b7c2dd8ca9dbdc3632e62d77e350dfccb5cea95fd0fd8a6467c616a2" target="_blank"><strong>Cesio, Mar&iacute;a Ver&oacute;nica</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cvsni/?urlId=efdc2e4d27c46568e51501a117c8d64c661d28215277fe2b1621ea4a392338f0bd55c3b410eb66c8bd85997e02d92a5828f529ff076bd0478d3b4ffd01ec2037&amp;convocatoria=21&amp;formato=html" target="_blank"><strong>Heinzen, Horacio</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?5a728c53379ba11edafc6029548ce29d65b0e495e64982b067a2707fc9d44e90fa33fc21f214f2d552656809bf896fdbcfece552c850bab35f4d18fc3812ebd9" target="_blank"><strong>Dellacassa, Eduardo</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?48a71d2e5134808569068d2724790a8aea8b2933a5fec257ee3e4e79c698c53217947faea852f59905ef92c97b0830d7d801d00a336d676bae44ed023b6adffa" target="_blank"><strong>Fern&aacute;ndez Fern&aacute;ndez, Adriana Maite</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?7c64fd0475a2077f15b2edfba26c864ffb58e74137469e728a10a1e9f597797565a168ad79a66a0e079ca1f99d19153126e8d3094144e8ab95c1a3e8ff5e8111" target="_blank"><strong>Medrano, Alejandra</strong></a>]]></dcterms:creator>
    <dcterms:source><![CDATA[Frontiers in nutrition, v.10, 2023.]]></dcterms:source>
    <dcterms:publisher><![CDATA[Frontiers]]></dcterms:publisher>
    <dcterms:date><![CDATA[2023]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya protege el derecho</strong>&nbsp;de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA -</strong>&nbsp;La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:extent><![CDATA[13 p.]]></dcterms:extent>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/6483">
    <dcterms:title><![CDATA[<strong>Tannat Grape Skin : A Feasible Ingredient for the Formulation of Snacks with Potential for Reducing the Risk of Diabetes</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[<span>VINOS</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>VINO TINTO</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>PROMOCION DE LA SALUD</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>BIODISPONIBILIDAD</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>NUTRICION</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>ORUJO DE UVA</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>DIABETES</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>BIBLIOGRAFIA NACIONAL QUIMICA</span>]]></dcterms:subject>
    <dcterms:subject><![CDATA[<span>2022</span>]]></dcterms:subject>
    <dcterms:abstract><![CDATA[In the present work the feasibility of Tannat grape skin (TGS) as a functional ingredient in the formulation of two snacks (yogurt and biscuits) was studied. The research provided novel information on the effects of the food matrix and digestion process, under simulated human oral gastrointestinal conditions, in the bioaccessibility of TGS bioactive compounds composing of the snacks with health promoting properties (antioxidant, anti-inflammatory, and antidiabetic). TGS polyphenolic profile was analyzed by ultra-high performance liquid chromatography tandem mass spectrometry (UHPLC-MS/MS) finding mainly flavonoids, phenolic acids, and anthocyanins, which may exert antioxidant, anti-inflammatory, and carbohydrase inhibition capacities. TGS digest showed antioxidant and antidiabetic potential compared to the undigested sample (p &lt; 0.05). Yogurt and biscuits with TGS were developed with the nutrition claims &ldquo;no-added sugars&rdquo; and &ldquo;source of fiber&rdquo; and were digested in vitro to evaluate the bioaccessibility of compounds with health promoting properties after food processing and digestion. After in vitro simulation of digestion, bioactive properties were enhanced for control and TGS snacks which may be attributed to the formation/release of compounds with health-promoting properties. Biscuits showed significant increase in ABTS antioxidant capacity and yogurt showed increased -glucosidase inhibition capacity by the addition of TGS (p &lt; 0.05). Polyphenols from TGS and bioactive peptides from snacks which may be released during digestion might be responsible for the observed bioactivities. Consumer&rsquo;s acceptance of TGS yogurt and biscuits showed scores of 6.3 and 5.1 (scale 1&ndash;9), respectively, showing TGS yogurt had higher overall acceptance. Sensory profile assessed by check-all-that-apply + just-about-right (CATA+JAR) showed most of the attributes were evaluated as &ldquo;just about right&rdquo;, supporting good food quality. The developed yogurt presented adequate shelf-life parameters for 28 days. TGS yogurt with higher acceptability showed reduced ROS formation (p &lt; 0.05) induced by tert-butyl hydroperoxide (1 mM) in CCD-18Co colon cells and RAW264.7 macrophages when pre-treated with concentrations 500&ndash;1000 and 100&ndash;500 g/mL of the digests, respectively. Moreover, TGS yogurt digest pre-treatment reduced nitric oxide (NO) production (p &lt; 0.05) in lipopolysaccharide (LPS)-induced RAW264.7 macrophages, showing anti-inflammatory potential. Bioactive peptides generated during lactic fermentation and digestion process may be contributors to intracellular effects. In conclusion, yogurt and biscuits with Tannat grape skin addition were obtained with nutrition claims &ldquo;no-added sugars&rdquo; and &ldquo;source of fiber&rdquo; with the potential to modulate key biochemical events associated with diabetes pathogenesis.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Fern&aacute;ndez Fern&aacute;ndez, Adriana Maite</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Dellacassa, Eduardo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Nardin, Tiziana</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Larcher, Roberto</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Iba&ntilde;ez, Cecilia</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Ter&aacute;n, Dahiana</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>G&aacute;mbaro, Adriana</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Medrano-Fernandez, Alejandra</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>del Castillo, Mar&iacute;a Dolores</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[Nutrientsv. 14, N&deg;419, 2022. -- e14030419. --]]></dcterms:source>
    <dcterms:publisher><![CDATA[MDPI]]></dcterms:publisher>
    <dcterms:date><![CDATA[2022]]></dcterms:date>
    <dcterms:rights><![CDATA[<p dir="ltr"><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p dir="ltr">(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p dir="ltr"><strong>La legislaci&oacute;n uruguaya protege el derecho de autor</strong>&nbsp;sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<span id="docs-internal-guid-9d2103f7-7fff-c813-00c7-2528fd4891ff"><strong>ADVERTENCIA:</strong>&nbsp;La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</span>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[<a href="https://doi.org/10.3390/nu14030419">10.3390/nu14030419</a>]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/4821">
    <dcterms:title><![CDATA[<strong>Targeted and untargeted high resolution mass approach for a putative profiling of glycosylated simple phenols in hybrid grapes</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[CROMATOGRAFIA LIQUIDA]]></dcterms:subject>
    <dcterms:subject><![CDATA[FENOLES GLICOSILADOS]]></dcterms:subject>
    <dcterms:subject><![CDATA[UVAS HIBRIDAS]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2017]]></dcterms:subject>
    <dcterms:abstract><![CDATA[Vitis vinifera is one of the most widespread grapevines around the world representing the raw material for high quality wine production. The availability of more resistant interspecific hybrid vine varieties, developed from crosses between Vitis vinifera and other Vitis species, has generated much interest, also due to the low environmental effect of production. However, hybrid grape wine composition and varietal differences between interspecific hybrids have not been well defined, particularly for the simple phenols profile. The dynamic of these phenols in wines, where the glycosylated forms can be transformed into the free ones during winemaking, also raises an increasing health interest by their role as antoxidants in wine consumers. In this work an on-line SPE clean-up device, to reduce matrix interference, was combined with ultra-high liquid chromatography-high resolution mass spectrometry in order to increase understanding of the phenolic composition of hybrid grape varieties. Specifically, the phenolic composition of 4 hybrid grape varieties (red, Cabernet Cantor and Prior; white, Muscaris and Solaris) and 2 European grape varieties (red, Merlot; white, Chardonnay) was investigated, focusing on free and glycosidically bound simple phenols and considering compound distribution in pulp, skin, seeds and wine. Using a targeted approach 53 free simple phenols and 7 glycosidic precursors were quantified with quantification limits ranging from 0.001 to 2 mg Kg&minus; 1 and calibration R2 of 0.99 for over 86% of compounds. The untargeted approach made it possible to tentatively identify 79 glycosylated precursors of selected free simple phenols in the form of -hexoside (N = 30), -pentoside (21), -hexoside-hexoside (17), -hexoside-pentoside (4), -pentoside-hexoside (5) and -pentoside-pentoside (2) derivatives on the basis of accurate mass, isotopic pattern and MS/MS fragmentation.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Barnaba, Chiara</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a title="Curriculum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=2df81feedac99473a4e536d2623f04c3" target="_blank"><strong>Dellacassa, Eduardo.</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Nicolini, Giorgio</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Giacomelli, Mattia</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Villegas, Tomas Roman</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Nardin, Tiziana</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Larcher, Roger</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[Food Research International v. 98, 2017. -- p. 20-33]]></dcterms:source>
    <dcterms:publisher><![CDATA[Elsevier]]></dcterms:publisher>
    <dcterms:date><![CDATA[2017]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya protege el derecho</strong> de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong> ADVERTENCIA -</strong> La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&egrave;s]]></dcterms:language>
    <dcterms:type><![CDATA[Artículo]]></dcterms:type>
    <dcterms:identifier><![CDATA[DOI: 10.1016/j.foodres.2017.01.011]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/6856">
    <dcterms:title><![CDATA[<strong>Tartrate fermentation with H2 production by a new member of Sporomusaceae enriched from rice paddy soil</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[METAGENOMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[ARROZ]]></dcterms:subject>
    <dcterms:subject><![CDATA[EMISIONES DE METANO]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2024]]></dcterms:subject>
    <dcterms:abstract><![CDATA[In rice paddies, soil and plant-derived organic matter are degraded anaerobically to methane (CH4), a powerful greenhouse gas. The highest rate of methane emission occurs during the reproductive stage of the plant when mostly dicarboxylic acids are exudated by the roots. The emission of methane at this stage depends largely on the cooperative interaction between dicarboxylic acid-fermenting bacteria and methanogenic archaea in the rhizosphere. The fermentation of tartrate, one of the major acids exudated, has been scarcely explored in rice paddy soils. In this work, we characterized an anaerobic consortium from rice paddy soil composed of four bacterial strains, whose principal member (LT8) can ferment tartrate, producing H2 and acetate. Tartrate fermentation was accelerated by co-inoculation with a hydrogenotrophic methanogen. The assembled genome of LT8 possesses a Na+-dependent oxaloacetate decarboxylase and shows that this bacterium likely invests part of the H2 produced to reduce NAD(P)+ to assimilate C from tartrate. The phylogenetic analysis of the 16S rRNA gene, the genome-based classification as well as the average amino acid identity (AAI) indicated that LT8 belongs to a new genus within the Sporomusaceae family. LT8 shares a few common features with its closest relatives, for which tartrate degradation has not been described. LT8 is limited to a few environments but is more common in rice paddy soils, where it might contribute to methane emissions from root exudates.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?e41ee09b825f22635cb8a1e9b42b334d75d1c2be0ccaad4f086d148a0ebac442b4a82cfb05ef977a8fe31965e28ee4bb8889f1ccb549f56f20a9403e2c02a0cf" target="_blank"><strong>Pereira-Mora, Luciana</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Guerrero, Leandro D.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Erijman, Leonardo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a href="https://export.cvuy.uy/cv/?7279b48461ca97fe00511d02458b69fcacbb55bc044daa2de78dca1ae0429329c37b6f39ecbe6c718f34baa0e533c04eee463fab4674161114edda6fcbba17c5" target="_blank"><strong>Fern&aacute;ndez-Scavino, Ana</strong></a>]]></dcterms:creator>
    <dcterms:source><![CDATA[Applied and Environmental Microbiology, v. 90, n&ordm; 4, 2024. -- e0235123]]></dcterms:source>
    <dcterms:publisher><![CDATA[American Society for Microbiology]]></dcterms:publisher>
    <dcterms:date><![CDATA[2024]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya protege el derecho</strong>&nbsp;de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA -</strong>&nbsp;La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:extent><![CDATA[14 p.]]></dcterms:extent>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[10.1128/aem.02351-23]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/2102">
    <dcterms:title><![CDATA[<strong>Tautomeric forms of 2-thiobarbituric acid as studied in the solid : in polar solutions</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[FISICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[RESONANCIA MAGNETICA NUCLEAR]]></dcterms:subject>
    <dcterms:subject><![CDATA[ESTRUCTURA MOLECULAR]]></dcterms:subject>
    <dcterms:subject><![CDATA[ESPECTROSCOPIA INFRAROJO]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2007]]></dcterms:subject>
    <dcterms:abstract><![CDATA[2-Thiobarbituric acid (TBA) coated gold nanoparticles (average diameter ) 5.90 nm) were produced and studied by several experimental and theoretical methods. As part of this study, the molecular structure of TBA tautomers in the solid, in polar solutions, and adsorbed onto gold nanoparticles was studied. The resolution of this complicated system (10 possible isomers) was accomplished with the aid of experimental (IR, UVvis, and NMR) and theoretical (DFT and MP2) methods. The general conclusion is that there are two preeminent isomers, N1 and N10, with different stabilities in different media. N1, the keto-thione tautomer, is the most stable in gas phase (&cent;Go 298  8-9 kcal/mol lower than the second-most stable isomer, depending on the method of calculation used). However, experimental spectroscopic data supported by the theoretical calculations strongly suggest an equilibrium between the tautomers N1 and N10 in methanol solution, where enolization of one keto group is produced by proton transfer from the methylene group, which is more acidic than the NH groups. With the use of the polarizable continuum method for simulating solvents, N10 is predicted to be even more stable than N1 by &cent;Go 298  1 kcal/mol in methanol. On the other hand, the IR spectrum of the solid can be best explained by assuming that only N10 is present, a fact also supported by the observation that the IR spectrum of TBA absorbed onto gold nanoparticles can be explained by a larger ratio of [N10]/ [N1] than that present in methanolic solution. Isomerization of N1H N10 can be explained by intervention of the solvent, proceeding faster in methanol solutions than in DMSO, where it is nevertheless observed after a time, according to the 13C NMR spectra. Our experiments support absorption of TBA onto gold nanoparticles through S-Au and N-Au interactions, with the preeminence of a N10-like enol structure. The experiments also demonstrate that the synthesized TBA-coated gold nanoparticles can autoassociate by hydrogen bonding to form larger structures. This same H-bonding capacity also assures that these coated nanoparticles act as thistles toward proteins in solution, binding them strongly, presumably not by chemical reaction but by a network of hydrogen bonds.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>M&eacute;ndez, Eduardo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Cerd&aacute;, Mar&iacute;a Fernanda</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a title="Curr&iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=fd97168d9e8b7d3f82474969b5b78453" target="_blank"><strong>Gancheff, Jorge S.</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a title="Curr&iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=b1b8a8c8b1a5835b874ac1994003c38d" target="_blank"><strong>Torres, Julia</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a title="Curr&iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=6f16399c452f7b13f8a01a148cb38e12" target="_blank"><strong>Kremer, Carlos</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a title="Curr&iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=94a8ff70d2730e3c95703f810fd79d7c" target="_blank"><strong>Castiglioni, J.</strong></a>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Kieninger, Martina</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<a title="Curr&iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=40f23b501897bd535c01b6602f1ea346" target="_blank"><strong>Ventura, Oscar N.</strong></a>]]></dcterms:creator>
    <dcterms:source><![CDATA[Journal of Physical Chemistry C v. 111, no. 8, 2007. -- p. 3369-3383]]></dcterms:source>
    <dcterms:publisher><![CDATA[American Chemical Society]]></dcterms:publisher>
    <dcterms:date><![CDATA[2007]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong> La legislaci&oacute;n uruguaya protege el derecho</strong> de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA -</strong> La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingles]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[DOI: 10.1021/jp0628176]]></dcterms:identifier>
</rdf:Description><rdf:Description rdf:about="https://riquim.fq.edu.uy/items/show/2753">
    <dcterms:title><![CDATA[<strong>Tautomerism and reactivity in heterocyclic N-Oxides. A spectrocopic and theoretical study of benzimidazole N-Oxide derivatives (N-Hydroxybenzimidazoles.</strong>]]></dcterms:title>
    <dcterms:subject><![CDATA[BENZIMIDAZOL]]></dcterms:subject>
    <dcterms:subject><![CDATA[BIBLIOGRAFIA NACIONAL QUIMICA]]></dcterms:subject>
    <dcterms:subject><![CDATA[2004]]></dcterms:subject>
    <dcterms:abstract><![CDATA[The tautomeric forms of benzimidazole N-oxide derivatives in solution were studied using nuclear magnetic resonance (NMR) techniques. Further insight into the molecular structures was provided by theoretical calculations using density functional theory (DFT). In the gas phase the N-hydroxy tautomer was more stable than the N-oxide, whereas in solution the stabilization of one form or the other depended on hydrogen bond formation involving the N-hydroxy/N-oxide moiety. Derivative 4 (n-butyl-5-nitrobenzimidazole-2-carboxamide 3-oxide), having a 2-carboxamide moiety, was the only compound studied present as a mixture of tautomers, the N-oxide being the predominant one. This was assigned to the formation of an internal hydrogen bond between the N-oxide group and the amide hydrogen atom. The tautomeric form present in the solid state was studied for derivative 1 (ethyl-5-nitrobenzimidazole-2-carboxylate 3-oxide) and was conclusively assigned by X-ray diffraction techniques to the N-hydroxy tautomer. In the crystal a strong O-H&acirc;&acirc;&acirc;N intermolecular bond gives rise to supramolecular polymeric chains in the lattice. This strong interaction was also seen in the infrared spectrum and was assigned to two broad bands at 2367 and 2526 cm-1. The vibrational spectrum was satisfactorily described by DFT calculations and an example of this is the prediction of the band corresponding to the N-O stretching (N-oxide) just 1% lower than the experimental value. Uncorrelated calculations (HF) were not able to give an unambiguous assignment of this band. The reaction of derivative 1 against different kinds of electrophiles, hard and soft, led only to O-substituted products. This result was explained in terms of the HSAB theory using a local-global approach.]]></dcterms:abstract>
    <dcterms:creator><![CDATA[<strong>Boiani Santurio, Mariana</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Cerecetto, Hugo</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Gonz&aacute;lez, Mercedes.</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Piro, Oscar E</strong>]]></dcterms:creator>
    <dcterms:creator><![CDATA[<strong>Castellano, Eduardo E</strong>]]></dcterms:creator>
    <dcterms:source><![CDATA[Journal of Physical Chemistry A v. 108, no. 51, 2004. -- p. 11241-11248]]></dcterms:source>
    <dcterms:publisher><![CDATA[American Chemical Society]]></dcterms:publisher>
    <dcterms:date><![CDATA[2004]]></dcterms:date>
    <dcterms:rights><![CDATA[<p><strong>Informaci&oacute;n sobre Derechos de Autor</strong></p>
<p>(Por favor lea este aviso antes de abrir los documentos u objetos)</p>
<p><strong>La legislaci&oacute;n uruguaya</strong> protege el derecho de autor sobre toda creaci&oacute;n literaria, cient&iacute;fica o art&iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&oacute;n a lo establecido por el derecho com&uacute;n y las siguientes leyes</p>
<p>(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)</p>
<p><strong>ADVERTENCIA</strong> - La consulta de este documento queda condicionada a la aceptaci&oacute;n de las siguientes condiciones de uso: Este documento es &uacute;nicamente para usos privados enmarcados en actividades de investigaci&oacute;n y docencia. No se autoriza su reproducci&oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&oacute;n o cita de partes debe indicarse el nombre de la persona autora.</p>
<p>&nbsp;</p>]]></dcterms:rights>
    <dcterms:format><![CDATA[PDF]]></dcterms:format>
    <dcterms:language><![CDATA[Ingl&eacute;s]]></dcterms:language>
    <dcterms:type><![CDATA[Art&iacute;culo]]></dcterms:type>
    <dcterms:identifier><![CDATA[DOI: 10.1021/jp046826v]]></dcterms:identifier>
</rdf:Description></rdf:RDF>
