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                <text>Tetrahedron Asymmetry v. 21, no. 5, 2010. -- p.631-635</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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&lt;p dir="ltr"&gt;&lt;span&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/span&gt;&lt;/p&gt;&#13;
&lt;p dir="ltr"&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derechode autor&lt;/strong&gt;&lt;span&gt;&amp;nbsp;sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/span&gt;&lt;/p&gt;&#13;
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                <text>The synthesis of new cyclic compounds, arylethanolamine derivatives, with potential beta3-adrenoceptor agonist selectivity, which are associated with thermogenesis and regulation of insulin release, are described. Oxazolidine, oxazolidin-2-one, and perhydro-1,4-oxazine derivatives were obtained. The preliminary evaluation of the pharmacological effects of some of the synthesized compounds showed an activation of lypolysis in rat adipocytes with potency and efficiency similar to that observed for other accredited beta3-adrenergic agonists.</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
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                <text>We describe the photoisomerization of hetero Diels&amp;ndash;Alder adducts of tetramethylpurpurogallin bearing b,c-unsaturated ketone chromophores and endocyclic &amp;ndash;N&amp;ndash;O&amp;ndash; or &amp;ndash;N&amp;ndash;N&amp;ndash; groups. Based on spectroscopic and crystallographic data, our results indicate that the outcome of the reaction for the two types of substrates can be correlated with the difference in the stabilities of the radical intermediates generated in each case. For oxazines, the photoisomerization involves both the b,c-unsaturated ketone and &amp;ndash;N&amp;ndash;O&amp;ndash; moieties, and proceeds through the formation of allyl, benzoyl, phenyl, and a-carbonyl radical intermediates. While the same allylic and benzoyl radicals are formed in adducts with an &amp;ndash;N&amp;ndash;N&amp;ndash; group, the hydrazine does not participate in the reaction and the product is a simple rearrangement of the initial intermediate.</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&amp;beta;-Galactosidase from Aspergillus oryzae offers a high yield for the synthesis of oligosaccharides&lt;br /&gt;derived from lactulose (OsLu) by transgalactosylation. Oligosaccharides with&lt;br /&gt;degree of polymerization (DP) &amp;ge; 3 have shown to possess higher in vitro bifidogenic effect&lt;br /&gt;than di- and tetrasaccharides. Thus, in this work, an optimization of reaction conditions&lt;br /&gt;affecting the specific selectivity of A. oryzae &amp;beta;-galactosidase for synthesis of OsLu has&lt;br /&gt;been carried out to enhance OsLu with DP &amp;ge; 3 production. Assays with &amp;beta;-galactosidase&lt;br /&gt;immobilized onto a glutaraldehyde&amp;ndash;agarose support were also carried out with the aim&lt;br /&gt;of making the process cost-effective and industrially viable. Optimal conditions with both&lt;br /&gt;soluble and immobilized enzyme for the synthesis of OsLu with DP &amp;ge; 3 were 50 &amp;deg;C, pH&lt;br /&gt;6.5, 450 g/L of lactulose, and 8 U/mL of enzyme, reaching yields of ca. 50% (w/v) of total&lt;br /&gt;OsLu and ca. 20% (w/v) of OsLu with DP 3, being 6&amp;prime;-galactosyl-lactulose the major one,&lt;br /&gt;after a short reaction time. Selective formation of disaccharides, however, was favored&lt;br /&gt;at 60 &amp;deg;C, pH 4.5, 450 g/L of lactulose and 8 U/mL of enzyme. Immobilization increased&lt;br /&gt;the enzymatic stability to temperature changes and allowed to reuse the enzyme. We&lt;br /&gt;can conclude that the use, under determined optimal conditions, of the A. oryzae &amp;beta;-galactosidase&lt;br /&gt;immobilized on a support of glutaraldehyde&amp;ndash;agarose constitutes an efficient&lt;br /&gt;and cost-effective alternative to the use of soluble &amp;beta;-galactosidases for the synthesis of&lt;br /&gt;prebiotic OsLu mixtures.</text>
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                <text>&lt;strong&gt;Cardelle-Cobas, Alejandra&lt;/strong&gt;</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>In the search for candidates of antiparasitic new drugs, macrocycle analogs and key fragments of aerucyclamides were obtained. The activities against Trypanosoma brucei brucei and cytotoxicities on murine macrophages (cell line J774) were evaluated. Two of the prepared compounds displayed similar anti-trypanosomal activities as aerucyclamides B and C. In addition, the compound with the highest activity presents a 150-fold selectivity (SI &amp;frac14; 150) for the parasite than against the murine macrophage</text>
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                <text>MedChemComm. v. 3, no 11, 2012. -- p. 1443-1448</text>
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                <text>&lt;p&gt;&amp;nbsp;&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>Herein, we describe an approach toward selenazole preparation based on the cycloisomerization of propargyl selenoamides. The selenoamides were synthesized in situ using the Ishihara reagent with spontaneous cyclization to form the 2,5-disubstituted selenazoles. Heterocylcles 9a-j were prepared using readily available starting materials, and yields ranged from moderate to good (20-80%). Methylselenazole 9a could be transformed into a bromomethyl derivative 13 using NBS. The intermediate 13 would provide a more versatile building block for further derivatizations, e.g., the cyanide 14.</text>
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                <text>Arbitrarily defined as organic salts with melting points below 1001C, ionic liquids (ILs) have gained considerable notoriety in the past decade. Owing to their negligible vapor pressure, thermal stability, and tunable solvent properties, these materials have found applications in a wide range of laboratory and industrial processes.1 As part of efforts aimed at better understanding the liquid structure of imidazolium-based ILs, we have shown that intraionic hydrogen-bonding (H-bonding) interactions in 1-n-butyl-3-methylimidazolium chloride ([C4mim]Cl (1), Figure 1) are evidenced by sizable deuterium isotope effects on the chloride ion 35/37Cl NMR signal (i.e. D35/37Cl(H,D)).2 Measurements obtained on the [C4mim]Cl isotopologues [2-d1]-[C4mim]Cl and [2,4,5-d3]-[C4mim]Cl led to D35/37Cl(H,D) values of up to 2 ppm, and corroborated the presence of H-bonds between the anion and the imidazolium cation protons on the C-2, C-4, and C-5 positions. Recent theoretical studies indicate that H-bonding between the anion and protons along the N-alkyl groups could also have an impact on the structure and dynamics of this class of ILs.3,4 Based on our previous results, these anion&amp;ndash;cation interactions could be detected experimentally by measurement of deuterium isotope effects on the 35/37Cl NMR signal of the chloride ion. For this purpose, we decided to synthesize a series of [C4mim]Cl deuterium isotopologues sequentially labeled along the N-alkyl group carbons (Figure 1a&amp;ndash;e). These could also be easily converted by metathesis to the corresponding tetrafluoroborate and hexafluorophosphate imidazolium salts (i.e. [C4mim]BF4 and [C4mim]PF6), which would be suitable for the study of interionic H-bonds through analysis of deuterium isotope effects on the 10/11B, 19F, and 31P signals of the BF! 4 and BF! 6 anions. In this manuscript we describe a strategy which uses similar routes to minimize the number of distinct reactions needed to prepare these compounds. As detailed below, good yields after the initial deuterium incorporation reaction were achieved in several cases through the combination of well-established chemical transformations into efficient single-step processes.</text>
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                <text>The Suzuki&amp;ndash;Miyaura cross-coupling reaction of a hydroxylated vinyl bromide obtained by a chemoenzymatic approach with a diverse range of potassium organotrifluoroborates has been accomplished catalyzed by Pd(PPh3)4 in satisfactory yields. A variety of functional groups are tolerated in the nucleophilic partner.</text>
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&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.</text>
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                <text>wo new mixed-valence iron complexes with 2-pyridyl oximes, [Fe(mpko)3Fe(H2O)2(NO3)](NO3)&amp;middot;2H2O (1) (mpko&amp;minus; = methyl(2-pyridyl)ketone oximate) and [{Fe(dpko)3}2Fe](ClO4)&amp;middot;4H2O (2) (dpko&amp;minus; = bis(2-pyridyl)ketone oximate), have been prepared by reaction of FeIII with mpkoH in methanol (1) and FeII with dpkoH in methanol/water (2). Dinuclear FeII(low-spin)FeIII(high-spin) and trinuclear FeII(low-spin)FeIII(high-spin)FeII(low-spin) cations are present in the crystal structure of 1 and 2, respectively. Intermolecular hydrogen bonds in 1 lead to weak antiferromagnetic interactions between pairs of neighboring FeIII centers, which allows observation of single-ion zero-field splitting effects. Keywords: Iron(II)/(III) complexes, methyl(2-pyridyl)ketone oxime, bis(2-pyridyl)ketone oxime, magnetic exchange mediated by hydrogen bonds, crystal structure Sample our Engineering &amp;amp; Technology journals, sign in here to start your access, latest two full volumes FREE to you for 14 days Publish open access with the Journal of Information and Telecommunications Sign up today for updates in your subject People also read Article Cu(II) complexes of cytosine and 1-methylcytosine with bromide: old motifs and new structures Rosaria Bruno et al. Journal of Coordination Chemistry Volume 71, 2018 - Issue 5 Published online: 23 Feb 2018 Article Structural studies on Ba(II) adducts of the cytosine nucleobase and its derivative 1-Methylcytosine Nadia Marino et al. Journal of Coordination Chemistry Volume 71, 2018 - Issue 6 Published online: 23 Feb 2018 Article Hexakis(dimethylformamide)iron(II) complex cation in hexahalorhenate(IV)-based salts: synthesis, X-ray structure and magnetic properties Carlos Rojas-Dotti et al. Journal of Coordination Chemistry Volume 71, 2018 - Issue 6 Published online: 19 Jan 2018 Article Iron(II) complex of 2-(1H-pyrazol-1-yl)pyridine-4-carboxylic acid (ppCOOH) suitable for surface deposition V&amp;iacute;ctor Garc&amp;iacute;a-L&amp;oacute;pez et al. Journal of Coordination Chemistry Volume 71, 2018 - Issue 6 Published online: 5 Feb 2018 Article A Zn(II) luminescent complex with a Schiff base ligand: solution, computational and solid state studies Sebasti&amp;aacute;n Mart&amp;iacute;nez et al. Journal of Coordination Chemistry Volume 71, 2018 - Issue 6 Published online: 19 Feb 2018 Article Magneto-structural correlations in asymmetric oxalato-bridged dicopper(II) complexes with polymethyl-substituted pyrazole ligands M. Luisa Calatayud et al. Journal of Coordination Chemistry Volume 71, 2018 - Issue 5 Published online: 12 Jan 2018</text>
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                <text>In this work, complexes containing mercaptothiazolines, and mono- and diphosphines with the general formula [Ru(N &amp;minus;S) 2 (P) 2 ] or [Ru(N &amp;minus;S) 2 (P-P)] &amp;ndash;N&amp;ndash;S &amp;minus;: 1,3-thiazoline-2-thionate (tzt &amp;minus;- a ) and benzo-1,3- thiazoline-2-thionate (bzoxt &amp;minus;- b ), and P 2 = monophosphine: P{ p -tol} 3 &amp;ndash;2 ; P-P = dppe &amp;ndash;3 , dppp &amp;ndash;4 , dppb &amp;ndash;5 , dppf &amp;ndash;6 or DPEPhos &amp;ndash;7 were synthesized. The complexes were characterized by 1 H and 31 P NMR, vibrational spectroscopy, elemental analysis, and the molecular structures of 3a, 4a, 5a, 6a &amp;bull;CH 2 Cl 2 and 7a were solved by X-ray diffraction. The Hirshfeld surface analysis and the 2D fingerprint plots were performed. The 1 H NMR spectra of the compounds revealed the signals of the ligands and the main feature is the absence of the N H signal of the protonated ligands TztH and BzoxtH supporting the coordi- nation in their anionic forms, which is also evidenced by the vibrational spectroscopy and molar conduc- tivity studies. The 31 P{ 1 H} NMR spectra present only one singlet indicating the chemical equivalence of both phosphorus nuclei and in a region compatible with phosphorus cis -positioned for the P( p -tol) 3 and for the potentially trans -spanning dppf and DPEPhos, whereas for the other diphosphines (dppe, dppp and dppb) only the cis -configuration is expected. The molecular structure revealed the Ru center is sited on a distorted octahedral geometry mainly as a consequence of the formation of four-membered chelate rings involving the N&amp;ndash;S &amp;minus;ligand. The coordination sphere is completed with two phosphorus atoms po- sitioned in a cis -fashion while trans to the nitrogen atoms of the tzt &amp;minus;ligand, and the remaining sulfur donors (thiolate) of tzt &amp;minus;ligand positioned trans to each other. The cyclic voltammograms of the com- plexes presented one monoelectronic and reversible process attributed to the Ru 3 + /Ru 2 + couple, and for the complexes with dppf an additional redox process is observed due to the Fe 3 + /Fe 2 + couple.</text>
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&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt;&amp;nbsp;de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt;&amp;nbsp;La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>We report the chemical synthesis route, structural characterization, and physical properties of nanofluid magnetic graphite �NFMG� obtained from the previously synthesized bulk organic magnetic graphite �MG� by stabilizing the aqueous ferrofluid suspension with an addition of active cationic surfactant. The measured magnetization-field hysteresis curves along with the temperature dependence of magnetization confirmed room-temperature ferromagnetism in both MG and NFMG samples.</text>
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                <text>Applied Physics Letters v. 95, no. 23, 2009. -- p. 233220/1-233220/3</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;strong&gt; &lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>The synthesis and microbiological evaluation of two new Ag(I) complexes with sulfamoxole (SMX), [Ag2(SMX)2]&amp;middot;H2O and [Ag4(SCN)3(SMX)]&amp;middot;H2O are described. Both were characterized by elemental analysis, thermogravimetry, powder and single crystal X-ray diffraction, NMR, Raman and experimental and theoretical IR spectroscopies. Their antibacterial and antifungal properties were evaluated by agar and broth dilution assays, respectively. In addition, synergism tests for Pseudomonas aeruginosa were performed, and genotoxicity studies were carried out employing the Allium cepa test. Both complexes displayed good activity against Escherichia coli, Staphylococcus aureus, P. aeruginosa, and 10 fungi strains, with lower minimum inhibitory concentrations (MICs) than that of free SMX in all cases. The nanometrical crystallite particle size determined from XRPD, DLS and TEM might explain the good microbiological activity in spite of the low solubility of both complexes. The fractional inhibitory concentration (FIC) calculated from the P. aeruginosa test data indicated that the activity of the complexes is not due to synergism of the free components in the concentration ratios studied. Moreover, none of the complexes displayed cytotoxic effects on onions in the concentration range tested, and chromosome aberrations were not observed.</text>
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                <text>Journal of Inorganic Biochemistry v. 141, 2014. -- p. 58-69</text>
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&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya&lt;/strong&gt; protege el derecho de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes&lt;/p&gt;&#13;
&lt;p&gt;(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&lt;strong&gt;Synthesis, crystal structure and magnetic properties of a novel heterobimetallic rhenium(IV)-dysprosium(III) chain&lt;/strong&gt;</text>
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                <text>The use of the mononuclear rhenium(IV) precursor [ReBr5 (H2 pydc)](-) (H2 pydc=3,5-pyridinedicarboxylic acid) as a metalloligand towards dysprosium(III) afforded the first heterobimetallic Re(IV) -Dy(III) complex. Crystal structures and static and dynamic magnetic properties of both rhenium-containing species are reported herein. The 5d-4f compound shows an extended 1D structure and the AC magnetic measurements reveal frequency dependence at low temperature suggesting slow relaxation of the magnetization.</text>
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                <text>&lt;strong&gt;Guedes, Guilherme P.&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Speziali, Nivaldo L.&lt;/strong&gt;</text>
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                <text>Chemistry - A European Journal v. 21, 2015. -- p. 8696-8700</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;&lt;strong&gt; ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>The syntheses, crystal structures and magnetic properties of four rhenium(IV) compounds of formulae NBu4[ReCl5(pyzCOOH)]&amp;middot;H2O (1), [ReCl5(&amp;micro;-pyzCOO)M(dmphen)2]&amp;middot;2CH3CN [M = Ni (2) and Co (3)] and {[ReCl5(&amp;micro;3-pyzCOO)]2Mn2(dmphen)3}n (4) (NBu4 = tetra-n-butylammonium cation, pyzCOOH = 2-pyrazinecarboxylic acid, dmphen = 2,9-dimethyl-1,10-phenanthroline) are reported herein. Compound 1 was obtained by the reaction of NBu4[ReCl5(dmf)] (dmf = dimethylformamide) with pyzCOOH in acetone, whereas the other complexes were obtained by the reaction of 1 with M(ClO4)2&amp;middot;6H2O [M = Ni (2), Co (3), Mn (4)] and dmphen in acetonitrile. Complex 1 is a mononuclear compound, 2 and 3 are neutral heterodinuclear complexes and 4 is a neutral chain in which each pyzCOO&amp;ndash; bridges one ReIV and two MnII in a very unusual &amp;micro;3-binding mode. Compounds 2 and 3 behave as magnetically isolated species with intramolecular ferromagnetic coupling between ReIV and NiII or ReIV and CoII ions, respectively. In turn, weak antiferromagnetic coupling between the MnII ions through anti-syn-carboxylate bridges together with weak ferromagnetism below 3.1 K due to small spin canting is observed in 4.</text>
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                <text>&lt;strong&gt;Armentano, Donatella&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;De Munno, Giovanni&lt;/strong&gt;</text>
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                <text>European Journal of Inorganic Chemistry no. 12, 2016. -- p. 1835-1845</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&lt;strong&gt;Synthesis, crystal structure and magnetic properties of novel heterobimetallic&lt;/strong&gt;&lt;br /&gt;&lt;strong&gt;malonate-bridged MIIReIV complexes (M = Mn, Fe, Co and Ni)&amp;dagger;&amp;Dagger;&lt;/strong&gt;</text>
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                <text>Three novel Re(IV) compounds, the mononuclear complex Bu4N[ReBr5(Hpyzc)] (1) and the heterobimetallic complexes [ReBr5(l-pyzc)M(dmphen)2]&amp;middot;2CH3CN [M = Co (2), Ni (3)] (Hpyzc = 2-pyrazinecarboxylic acid, dmphen = 2,9-dimethyl-1,10-phenanthroline), have been synthesized and their crystal structures determined by single-crystal X-ray diffraction. The structure of 1 consists of [ReBr5(Hpyzc)]&amp;minus; complex anions and tetrabutylammonium cations, Bu4N+. TheRe(IV) is surrounded by five bromide anions and a N-donor Hpyzc monodentate ligand, in a distorted octahedral environment. The structures of 2 and 3 consist of dinuclear units [ReBr5(l-pyzc)M(dmphen)2], with the metal ions linked by a pyzc bridge ligand, being bidentate toward M(II) and monodentate toward Re(IV). The environment of Re(IV) is the same as in 1, whereasM(II) is six-coordinate, being surrounded by four nitrogen atoms of two bidentate dmphen ligands and one oxygen atom and one nitrogen atom of the pyzc anion. The magnetic properties of 1&amp;ndash;3 were investigated in the temperature range 2.0&amp;ndash;300 K. 1 shows the expected magnetic behavior for a mononuclear Re(IV) complex with a weak intermolecular antiferromagnetic coupling at low temperatures. The bimetallic complexes exhibit an intramolecular ferromagnetic coupling between Re(IV) and the M(II) ion (Co, Ni).</text>
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                <text>&lt;a title="Curr&amp;iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=0887bbd8061f3cad6738a2689bdda9f6" target="_blank"&gt;&lt;strong&gt;Cuevas, Alicia&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;strong&gt;&lt;a title="Curr&amp;iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=6f16399c452f7b13f8a01a148cb38e12" target="_blank"&gt;Kremer, Carlos&lt;/a&gt;&lt;/strong&gt;</text>
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                <text>&lt;a title="Curr&amp;iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=8b1a957170f0b5988597d2cc3d6f732b" target="_blank"&gt;&lt;strong&gt;Suescun, Leopoldo&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;strong&gt;Russi, Silvia&lt;/strong&gt;</text>
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                <text>Dalton Transactions&amp;nbsp; no. 45, 2007. -- p. 5305-5315</text>
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                <text>Royal Society of Chemistry</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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          <description>If the image is of an object, state the type of object, such as painting, sculpture, paper, photo, and additional data</description>
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          <element elementId="50">
            <name>Title</name>
            <description>A name given to the resource</description>
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                <text>&lt;strong&gt;Synthesis, crystal structure and magnetic properties of the Re(II) complexes NBu4[Re(NO)Br4(L)] (L = pyridine and diazine type ligands)&lt;/strong&gt;</text>
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          <element elementId="49">
            <name>Subject</name>
            <description>The topic of the resource</description>
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              <elementText elementTextId="453000">
                <text>COMPLEJOS</text>
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              <elementText elementTextId="453001">
                <text>ESTRUCTURA CRISTALINA</text>
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                <text>SINTESIS</text>
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              <elementText elementTextId="453003">
                <text>BIBLIOGRAFIA NACIONAL QUIMICA</text>
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              <elementText elementTextId="453004">
                <text>2013</text>
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            <name>Abstract</name>
            <description>A summary of the resource.</description>
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              <elementText elementTextId="453005">
                <text>Four novel Re(II) complexes of formula NBu4[Re(NO)Br4(L)] [NBu4+ = tetra-n-butylammonium cation and L = pyridine (1), pyrazine (2), pyrimidine (3), pyridazine (4)] have been prepared by a substitution reaction involving NBu4[Re(NO)Br4(EtOH)] and L. Their crystal structures have been determined by single crystal X-ray diffraction. They are all mononuclear complexes whose structure is made up of [Re(NO)Br4L]&amp;minus; anions and NBu4+ cations. Each Re(II) ion is six-coordinate with four bromide ligands, a linear nitrosyl group and one monodentate nitrogen donor L building a tetragonally distorted octahedral surrounding. The Re&amp;ndash;Br bond distances cover a narrow range [2.5048(8)&amp;ndash;2.5333(5) &amp;Aring;] and they are longer than the Re&amp;ndash;NO [1.688(15)&amp;ndash;1.736(3) &amp;Aring;] and Re&amp;ndash;N bonds [2.219(4)&amp;ndash;2.234(3) &amp;Aring;]. The magnetic properties of 1&amp;ndash;4 have been investigated in the temperature range 1.9&amp;ndash;295 K. They behave like quasi magnetically isolated spin doublets with very weak antiferromagnetic interactions through intermolecular Br⋯Br contacts. Their magnetic properties are discussed through a deep analysis of the influence of the ligand field, spin&amp;ndash;orbit coupling, tetragonal distortion and covalence effects. The values of the temperature-independent paramagnetism for 1&amp;ndash;4 are also substantiated and compared to those previously reported in related systems.&lt;br /&gt;&lt;br /&gt;</text>
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          <element elementId="39">
            <name>Creator</name>
            <description>An entity primarily responsible for making the resource</description>
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              <elementText elementTextId="453006">
                <text>&lt;strong&gt;Pacheco, Mario&lt;/strong&gt;</text>
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                <text>&lt;a title="Curriculum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=0887bbd8061f3cad6738a2689bdda9f6" target="_blank"&gt;&lt;strong&gt;Cuevas, Alicia&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;strong&gt;Gonz&amp;aacute;lez-Platas, Javier&lt;/strong&gt;</text>
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              <elementText elementTextId="453009">
                <text>&lt;a title="Curriculum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=fc7cd71892b1a9968ee19230dafdbd01" target="_blank"&gt;&lt;strong&gt;Faccio, Ricardo&lt;/strong&gt;&lt;/a&gt;</text>
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              <elementText elementTextId="453010">
                <text>&lt;strong&gt;Lloret, Francesc&lt;/strong&gt;</text>
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              <elementText elementTextId="453011">
                <text>&lt;strong&gt;Julve, Miguel&lt;/strong&gt;</text>
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              <elementText elementTextId="453012">
                <text>&lt;a title="Curriculum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=6f16399c452f7b13f8a01a148cb38e12" target="_blank"&gt;&lt;strong&gt;Kremer, Carlos&lt;/strong&gt;&lt;/a&gt;</text>
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          <element elementId="48">
            <name>Source</name>
            <description>A related resource from which the described resource is derived</description>
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              <elementText elementTextId="453013">
                <text>Dalton Transactions v. 42, no. 43, 2013. -- p. 15361-15371</text>
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          <element elementId="45">
            <name>Publisher</name>
            <description>An entity responsible for making the resource available</description>
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              <elementText elementTextId="453014">
                <text>Royal Society of Chemistry</text>
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            </elementTextContainer>
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          <element elementId="40">
            <name>Date</name>
            <description>A point or period of time associated with an event in the lifecycle of the resource</description>
            <elementTextContainer>
              <elementText elementTextId="453015">
                <text>2013</text>
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          <element elementId="47">
            <name>Rights</name>
            <description>Information about rights held in and over the resource</description>
            <elementTextContainer>
              <elementText elementTextId="453016">
                <text>&lt;p style="margin-bottom: 0cm;"&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;br /&gt;&lt;br /&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;br /&gt;&lt;br /&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya&lt;/strong&gt; protege el derecho de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes&lt;br /&gt;&lt;br /&gt;(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;br /&gt;&lt;br /&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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            <name>Format</name>
            <description>The file format, physical medium, or dimensions of the resource</description>
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              <elementText elementTextId="453017">
                <text>PDF</text>
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            <name>Language</name>
            <description>A language of the resource</description>
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              <elementText elementTextId="453018">
                <text>Ingl&amp;eacute;s</text>
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            <name>Type</name>
            <description>The nature or genre of the resource</description>
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              <elementText elementTextId="453019">
                <text>Art&amp;iacute;culo</text>
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            <name>Identifier</name>
            <description>An unambiguous reference to the resource within a given context</description>
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              <elementText elementTextId="453020">
                <text>DOI: 10.1039/C3DT51699G</text>
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        <name>Complejos</name>
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        <name>Estructura cristalina</name>
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        <name>Síntesis</name>
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