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                <text>&lt;p&gt;&lt;strong&gt;&lt;em&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/em&gt;&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;em&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt;&lt;/em&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&lt;strong&gt;T908 Polymeric Micelles Improved the Uptake of Sgc8-c Aptamer Probe in Tumor-Bearing Mice: A Co-Association Study between the Probe and Preformed Nanostructures&lt;/strong&gt;</text>
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                <text>Aptamers are oligonucleotides that have the characteristic of recognizing a target with high affinity and specificity. Based on our previous studies, the aptamer probe Sgc8-c-Alexa647 is a promising tool for molecular imaging of PTK7, which is an interesting biomarker in cancer. In order to improve the delivery of this probe as well as create a novel drug delivery nanosystem targeted to the PTK7 receptor, we evaluate the co-association between the probe and preformed nanostructures. In this work, preformed pegylated liposomes (PPL) and linear and branched pristine polymeric micelles (PMs), based on PEO&amp;ndash;PPO&amp;ndash;PEO triblock copolymers were used: poloxamer F127&amp;reg; and poloxamines T1307&amp;reg; and T908&amp;reg;. For it, Sgc8-c-Alexa647 and its co-association with the different nanostructures was exhaustively analyzed. DLS analysis showed nanometric sizes, and TEM and AFM showed notable differences between free- and co-associated probe. Likewise, all nanosystems were evaluated on A20 lymphoma cell line overexpressing PTK7, and the confocal microscopy images showed distinctness in cellular uptake. Finally, the biodistribution in BALB/c mice bearing lymphoma-tumor and pharmacokinetic study revealed an encouraging profile for T908-probe. All data obtained from this work suggested that PMs and, more specifically T908 ones, are good candidates to improve the pharmacokinetics and the tumor uptake of aptamer-based probes.</text>
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                <text>&lt;p&gt;The use of biocatalysts in fuel industry is an interesting and greener alternative. In this connection, it was found&lt;br /&gt;that the chain-length selectivity profile of a solvent-tolerant lipase activity fromAspergillus nigerMYA 135 determined&lt;br /&gt;in both hydrolytic and synthetic reactions depended on theway that the enzymewas prepared. Indeed, a&lt;br /&gt;mycelium-bound (Mb) lipase activity obtained either in presence or absence of 2% olive oil as well as a lyophilized&lt;br /&gt;supernatant extract obtained in presence of 2% olive oil showed different specificity constants (1/&amp;alpha;).&lt;br /&gt;Thus, the highest substrate specificity in hydrolysis reaction was observed toward a long-chain fatty acid (C18;&lt;br /&gt;1/&amp;alpha;=1.0) with the constitutive Mb-lipase in organic medium. In addition, this lipase preparation was specific&lt;br /&gt;toward the synthesis of methyl palmitate during esterification (1/&amp;alpha;=1.00) and ethyl palmitate in transesterification&lt;br /&gt;(1/&amp;alpha;=0.93). Interestingly, the induced Mb-lipase was a highly reactive biocatalyst preparation in both&lt;br /&gt;transesterification (58% of the reactions displayed 1/&amp;alpha;&amp;gt;0.5) and esterification (88% of the reactions displayed&lt;br /&gt;1/&amp;alpha;&amp;gt;0.7) reactions. On the contrary, the induced lyophilized supernatant was the most specific enzymatic&lt;br /&gt;system showing a clear preference for linoleic acid in esterification reactions (1/&amp;alpha; around of 0.77 for all acyl&lt;br /&gt;acceptors tested).&lt;/p&gt;</text>
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&lt;p style="margin-bottom: 0cm;"&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;&#13;
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                <text>&lt;strong&gt;Tailoring mixed-valence CoIII/FeII complexes for their potential use as sensitizers in dye sensitized solar cells&lt;/strong&gt;</text>
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                <text>Dinuclear class II CoIII/FeII mixed-valence complexes of type [LnCoIII(m-NC)FeII(CN)3L2]m� (where Ln represents a pentadentate macrocycle and L2 a bpy ligand or two cyanides) have electronic properties that make them possible sensitizers in DSSC (dye sensitized solar cells). For this purpose the new complex Na2[{trans-L14COOCoIII(m-NC)}FeII(CN)5] has been prepared and characterized by the usual methods and its sensitizer properties compared with those of the already known [{trans-L15CoIII(m-NC)}FeII(CN)3(bipy)eq,ax](ClO4). The complex [{trans- L14COOCoIII(m-NC)}FeII(CN)5]2� has been designed for the actuation of an electron injection from the cobalt centre on MMCT, while the [{trans-LnCoIII(m-NC)}FeII(CN)3(bipy)]+ structure can produce a tuned injection from the iron centre via an MLCT electronic state, as described for similar systems. The characterization on solid oxide semiconductor supports has been carried out for these two complexes and the results have been compared with the behaviour observed in aqueous solution and in solvents of varying polarities. Their use in DSSC has been checked and, while a sensitizer response is observed for [{trans-L14COOCoIII(m-NC)}FeII(CN)5]2�, complex [{trans-L15CoIII(m-NC)}FeII(CN)3(bipy)eq,ax]+ does not produce any electrical current on illumination. The low efficiency of the built DSSC can be easily related both with the very low value of the extinction coefficient of the MMCT band responsible for the electron injection, and with the small driving force for the reduction of the complex with the standard I2/I3� system used after electron injection.</text>
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                <text>New Journal of Chemistry v. 32, no. 4, 2008. -- p. 705-711</text>
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                <text>Royal Society of Chemistry</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya&lt;/strong&gt; protege el derecho de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes&lt;/p&gt;&#13;
&lt;p&gt;(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>There is a worldwide trend to understand the impact of non-Saccharomyces yeast species on the process of winemaking. Although the predominant species at the end of the fermentation is Saccharomyces cerevisiae, several non-Saccharomyces species present during the first days of the process can produce and/or release aromas that improve the bouquet and complexity of the final wine. Since no genomic sequences are available for the predominant non-Saccharomyces species selected from grapes or musts (Hanseniaspora uvarum, Hanseniaspora vineae, Hanseniaspora opuntiae, Metschnikowia pulcherrima, Candida zemplinina), a reproducible PCR method was devised to discriminate strains at the subspecies level. The method combines different oligonucleotides based on tandem repeats with a second oligonucleotide based on a conserved tRNA region, specific for ascomycetes. Tandem repeats are randomly dispersed in all eukaryotic genomes and tRNA genes are conserved and present in several copies in different chromosomes. As an example, the method was applied to discriminate native M. pulcherrima strains but it could be extended to differentiate strains from other non-Saccharomyces species. The biodiversity of species and strains found in the grape ecosystem is a potential source of new enzymes, fungicides and/or novel sustainable methods for biological control of phytopathogens.</text>
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                <text>&lt;strong&gt;Tannat Grape Skin : A Feasible Ingredient for the Formulation of Snacks with Potential for Reducing the Risk of Diabetes&lt;/strong&gt;</text>
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                <text>&lt;span&gt;VINOS&lt;/span&gt;</text>
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                <text>&lt;span&gt;VINO TINTO&lt;/span&gt;</text>
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                <text>&lt;span&gt;PROMOCION DE LA SALUD&lt;/span&gt;</text>
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                <text>&lt;span&gt;BIODISPONIBILIDAD&lt;/span&gt;</text>
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                <text>&lt;span&gt;NUTRICION&lt;/span&gt;</text>
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                <text>&lt;span&gt;ORUJO DE UVA&lt;/span&gt;</text>
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                <text>&lt;span&gt;DIABETES&lt;/span&gt;</text>
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                <text>&lt;span&gt;BIBLIOGRAFIA NACIONAL QUIMICA&lt;/span&gt;</text>
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                <text>&lt;span&gt;2022&lt;/span&gt;</text>
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                <text>In the present work the feasibility of Tannat grape skin (TGS) as a functional ingredient in the formulation of two snacks (yogurt and biscuits) was studied. The research provided novel information on the effects of the food matrix and digestion process, under simulated human oral gastrointestinal conditions, in the bioaccessibility of TGS bioactive compounds composing of the snacks with health promoting properties (antioxidant, anti-inflammatory, and antidiabetic). TGS polyphenolic profile was analyzed by ultra-high performance liquid chromatography tandem mass spectrometry (UHPLC-MS/MS) finding mainly flavonoids, phenolic acids, and anthocyanins, which may exert antioxidant, anti-inflammatory, and carbohydrase inhibition capacities. TGS digest showed antioxidant and antidiabetic potential compared to the undigested sample (p &amp;lt; 0.05). Yogurt and biscuits with TGS were developed with the nutrition claims &amp;ldquo;no-added sugars&amp;rdquo; and &amp;ldquo;source of fiber&amp;rdquo; and were digested in vitro to evaluate the bioaccessibility of compounds with health promoting properties after food processing and digestion. After in vitro simulation of digestion, bioactive properties were enhanced for control and TGS snacks which may be attributed to the formation/release of compounds with health-promoting properties. Biscuits showed significant increase in ABTS antioxidant capacity and yogurt showed increased �-glucosidase inhibition capacity by the addition of TGS (p &amp;lt; 0.05). Polyphenols from TGS and bioactive peptides from snacks which may be released during digestion might be responsible for the observed bioactivities. Consumer&amp;rsquo;s acceptance of TGS yogurt and biscuits showed scores of 6.3 and 5.1 (scale 1&amp;ndash;9), respectively, showing TGS yogurt had higher overall acceptance. Sensory profile assessed by check-all-that-apply + just-about-right (CATA+JAR) showed most of the attributes were evaluated as &amp;ldquo;just about right&amp;rdquo;, supporting good food quality. The developed yogurt presented adequate shelf-life parameters for 28 days. TGS yogurt with higher acceptability showed reduced ROS formation (p &amp;lt; 0.05) induced by tert-butyl hydroperoxide (1 mM) in CCD-18Co colon cells and RAW264.7 macrophages when pre-treated with concentrations 500&amp;ndash;1000 and 100&amp;ndash;500 �g/mL of the digests, respectively. Moreover, TGS yogurt digest pre-treatment reduced nitric oxide (NO) production (p &amp;lt; 0.05) in lipopolysaccharide (LPS)-induced RAW264.7 macrophages, showing anti-inflammatory potential. Bioactive peptides generated during lactic fermentation and digestion process may be contributors to intracellular effects. In conclusion, yogurt and biscuits with Tannat grape skin addition were obtained with nutrition claims &amp;ldquo;no-added sugars&amp;rdquo; and &amp;ldquo;source of fiber&amp;rdquo; with the potential to modulate key biochemical events associated with diabetes pathogenesis.</text>
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                <text>&lt;strong&gt;Fern&amp;aacute;ndez Fern&amp;aacute;ndez, Adriana Maite&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Dellacassa, Eduardo&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Nardin, Tiziana&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Larcher, Roberto&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Iba&amp;ntilde;ez, Cecilia&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Ter&amp;aacute;n, Dahiana&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;G&amp;aacute;mbaro, Adriana&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Medrano-Fernandez, Alejandra&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;del Castillo, Mar&amp;iacute;a Dolores&lt;/strong&gt;</text>
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                <text>Nutrientsv. 14, N&amp;deg;419, 2022. -- e14030419. --</text>
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                <text>MDPI</text>
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              <elementText elementTextId="637304">
                <text>2022</text>
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            <name>Rights</name>
            <description>Information about rights held in and over the resource</description>
            <elementTextContainer>
              <elementText elementTextId="637305">
                <text>&lt;p dir="ltr"&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p dir="ltr"&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p dir="ltr"&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho de autor&lt;/strong&gt;&amp;nbsp;sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;span id="docs-internal-guid-9d2103f7-7fff-c813-00c7-2528fd4891ff"&gt;&lt;strong&gt;ADVERTENCIA:&lt;/strong&gt;&amp;nbsp;La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/span&gt;</text>
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                <text>Ingl&amp;eacute;s</text>
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                <text>Art&amp;iacute;culo</text>
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            <name>Identifier</name>
            <description>An unambiguous reference to the resource within a given context</description>
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              <elementText elementTextId="637309">
                <text>&lt;a href="https://doi.org/10.3390/nu14030419"&gt;10.3390/nu14030419&lt;/a&gt;</text>
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      <tag tagId="897">
        <name>Biodisponibilidad</name>
      </tag>
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        <name>Diabetes</name>
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      <tag tagId="344">
        <name>Nutrición</name>
      </tag>
      <tag tagId="4759">
        <name>Orujo de Uva</name>
      </tag>
      <tag tagId="7266">
        <name>Promoción de la salud</name>
      </tag>
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        <name>Vino tinto</name>
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        <name>Vinos</name>
      </tag>
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                    <text>3</text>
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            <element elementId="50">
              <name>Title</name>
              <description>A name given to the resource</description>
              <elementTextContainer>
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                  <text>Bibliografía Nacional Química</text>
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              <name>Description</name>
              <description>An account of the resource</description>
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                <elementText elementTextId="709198">
                  <text>Contiene la producción científica nacional de los profesionales químicos e investigadores, durante el período 1929 hasta la fecha.</text>
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                  <text>Departamento de Documentación y Biblioteca</text>
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          <name>Original Format</name>
          <description>If the image is of an object, state the type of object, such as painting, sculpture, paper, photo, and additional data</description>
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                <text>&lt;strong&gt;Targeted and untargeted high resolution mass approach for a putative profiling of glycosylated simple phenols in hybrid grapes&lt;/strong&gt;</text>
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            <name>Subject</name>
            <description>The topic of the resource</description>
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                <text>CROMATOGRAFIA LIQUIDA</text>
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                <text>FENOLES GLICOSILADOS</text>
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                <text>UVAS HIBRIDAS</text>
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                <text>BIBLIOGRAFIA NACIONAL QUIMICA</text>
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                <text>2017</text>
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            <name>Abstract</name>
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                <text>Vitis vinifera is one of the most widespread grapevines around the world representing the raw material for high quality wine production. The availability of more resistant interspecific hybrid vine varieties, developed from crosses between Vitis vinifera and other Vitis species, has generated much interest, also due to the low environmental effect of production. However, hybrid grape wine composition and varietal differences between interspecific hybrids have not been well defined, particularly for the simple phenols profile. The dynamic of these phenols in wines, where the glycosylated forms can be transformed into the free ones during winemaking, also raises an increasing health interest by their role as antoxidants in wine consumers. In this work an on-line SPE clean-up device, to reduce matrix interference, was combined with ultra-high liquid chromatography-high resolution mass spectrometry in order to increase understanding of the phenolic composition of hybrid grape varieties. Specifically, the phenolic composition of 4 hybrid grape varieties (red, Cabernet Cantor and Prior; white, Muscaris and Solaris) and 2 European grape varieties (red, Merlot; white, Chardonnay) was investigated, focusing on free and glycosidically bound simple phenols and considering compound distribution in pulp, skin, seeds and wine. Using a targeted approach 53 free simple phenols and 7 glycosidic precursors were quantified with quantification limits ranging from 0.001 to 2 mg Kg&amp;minus; 1 and calibration R2 of 0.99 for over 86% of compounds. The untargeted approach made it possible to tentatively identify 79 glycosylated precursors of selected free simple phenols in the form of -hexoside (N = 30), -pentoside (21), -hexoside-hexoside (17), -hexoside-pentoside (4), -pentoside-hexoside (5) and -pentoside-pentoside (2) derivatives on the basis of accurate mass, isotopic pattern and MS/MS fragmentation.</text>
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            <name>Creator</name>
            <description>An entity primarily responsible for making the resource</description>
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                <text>&lt;strong&gt;Barnaba, Chiara&lt;/strong&gt;</text>
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                <text>&lt;a title="Curriculum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=2df81feedac99473a4e536d2623f04c3" target="_blank"&gt;&lt;strong&gt;Dellacassa, Eduardo.&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;strong&gt;Nicolini, Giorgio&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Giacomelli, Mattia&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Villegas, Tomas Roman&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Nardin, Tiziana&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Larcher, Roger&lt;/strong&gt;</text>
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            <name>Source</name>
            <description>A related resource from which the described resource is derived</description>
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                <text>Food Research International v. 98, 2017. -- p. 20-33</text>
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            <name>Publisher</name>
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                <text>Elsevier</text>
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                <text>2017</text>
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            <name>Rights</name>
            <description>Information about rights held in and over the resource</description>
            <elementTextContainer>
              <elementText elementTextId="459647">
                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&lt;strong&gt;Tartrate fermentation with H2 production by a new member of Sporomusaceae enriched from rice paddy soil&lt;/strong&gt;</text>
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                <text>EMISIONES DE METANO</text>
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                <text>2024</text>
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                <text>In rice paddies, soil and plant-derived organic matter are degraded anaerobically to methane (CH4), a powerful greenhouse gas. The highest rate of methane emission occurs during the reproductive stage of the plant when mostly dicarboxylic acids are exudated by the roots. The emission of methane at this stage depends largely on the cooperative interaction between dicarboxylic acid-fermenting bacteria and methanogenic archaea in the rhizosphere. The fermentation of tartrate, one of the major acids exudated, has been scarcely explored in rice paddy soils. In this work, we characterized an anaerobic consortium from rice paddy soil composed of four bacterial strains, whose principal member (LT8) can ferment tartrate, producing H2 and acetate. Tartrate fermentation was accelerated by co-inoculation with a hydrogenotrophic methanogen. The assembled genome of LT8 possesses a Na+-dependent oxaloacetate decarboxylase and shows that this bacterium likely invests part of the H2 produced to reduce NAD(P)+ to assimilate C from tartrate. The phylogenetic analysis of the 16S rRNA gene, the genome-based classification as well as the average amino acid identity (AAI) indicated that LT8 belongs to a new genus within the Sporomusaceae family. LT8 shares a few common features with its closest relatives, for which tartrate degradation has not been described. LT8 is limited to a few environments but is more common in rice paddy soils, where it might contribute to methane emissions from root exudates.</text>
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                <text>&lt;a href="https://export.cvuy.uy/cv/?e41ee09b825f22635cb8a1e9b42b334d75d1c2be0ccaad4f086d148a0ebac442b4a82cfb05ef977a8fe31965e28ee4bb8889f1ccb549f56f20a9403e2c02a0cf" target="_blank"&gt;&lt;strong&gt;Pereira-Mora, Luciana&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;strong&gt;Guerrero, Leandro D.&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Erijman, Leonardo&lt;/strong&gt;</text>
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                <text>&lt;a href="https://export.cvuy.uy/cv/?7279b48461ca97fe00511d02458b69fcacbb55bc044daa2de78dca1ae0429329c37b6f39ecbe6c718f34baa0e533c04eee463fab4674161114edda6fcbba17c5" target="_blank"&gt;&lt;strong&gt;Fern&amp;aacute;ndez-Scavino, Ana&lt;/strong&gt;&lt;/a&gt;</text>
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            <description>A related resource from which the described resource is derived</description>
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                <text>Applied and Environmental Microbiology, v. 90, n&amp;ordm; 4, 2024. -- e0235123</text>
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            <description>An entity responsible for making the resource available</description>
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                <text>American Society for Microbiology</text>
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            <name>Date</name>
            <description>A point or period of time associated with an event in the lifecycle of the resource</description>
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              <elementText elementTextId="706186">
                <text>2024</text>
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            <name>Rights</name>
            <description>Information about rights held in and over the resource</description>
            <elementTextContainer>
              <elementText elementTextId="706187">
                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt;&amp;nbsp;de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt;&amp;nbsp;La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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              <elementText elementTextId="706188">
                <text>PDF</text>
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            <name>Extent</name>
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                <text>14 p.</text>
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            <name>Language</name>
            <description>A language of the resource</description>
            <elementTextContainer>
              <elementText elementTextId="706190">
                <text>Ingl&amp;eacute;s</text>
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            <name>Identifier</name>
            <description>An unambiguous reference to the resource within a given context</description>
            <elementTextContainer>
              <elementText elementTextId="706192">
                <text>10.1128/aem.02351-23</text>
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        <name>Metagenómica</name>
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              <name>Title</name>
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                  <text>Bibliografía Nacional Química</text>
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              <description>An account of the resource</description>
              <elementTextContainer>
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                  <text>Contiene la producción científica nacional de los profesionales químicos e investigadores, durante el período 1929 hasta la fecha.</text>
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              <elementTextContainer>
                <elementText elementTextId="709199">
                  <text>Departamento de Documentación y Biblioteca</text>
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          <element elementId="50">
            <name>Title</name>
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                <text>&lt;strong&gt;Tautomeric forms of 2-thiobarbituric acid as studied in the solid : in polar solutions&lt;/strong&gt;</text>
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            <name>Subject</name>
            <description>The topic of the resource</description>
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                <text>FISICA</text>
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                <text>RESONANCIA MAGNETICA NUCLEAR</text>
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                <text>ESTRUCTURA MOLECULAR</text>
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                <text>ESPECTROSCOPIA INFRAROJO</text>
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                <text>BIBLIOGRAFIA NACIONAL QUIMICA</text>
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                <text>2007</text>
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                <text>2-Thiobarbituric acid (TBA) coated gold nanoparticles (average diameter ) 5.90 nm) were produced and studied by several experimental and theoretical methods. As part of this study, the molecular structure of TBA tautomers in the solid, in polar solutions, and adsorbed onto gold nanoparticles was studied. The resolution of this complicated system (10 possible isomers) was accomplished with the aid of experimental (IR, UVvis, and NMR) and theoretical (DFT and MP2) methods. The general conclusion is that there are two preeminent isomers, N1 and N10, with different stabilities in different media. N1, the keto-thione tautomer, is the most stable in gas phase (&amp;cent;Go 298 � 8-9 kcal/mol lower than the second-most stable isomer, depending on the method of calculation used). However, experimental spectroscopic data supported by the theoretical calculations strongly suggest an equilibrium between the tautomers N1 and N10 in methanol solution, where enolization of one keto group is produced by proton transfer from the methylene group, which is more acidic than the NH groups. With the use of the polarizable continuum method for simulating solvents, N10 is predicted to be even more stable than N1 by &amp;cent;Go 298 � 1 kcal/mol in methanol. On the other hand, the IR spectrum of the solid can be best explained by assuming that only N10 is present, a fact also supported by the observation that the IR spectrum of TBA absorbed onto gold nanoparticles can be explained by a larger ratio of [N10]/ [N1] than that present in methanolic solution. Isomerization of N1H N10 can be explained by intervention of the solvent, proceeding faster in methanol solutions than in DMSO, where it is nevertheless observed after a time, according to the 13C NMR spectra. Our experiments support absorption of TBA onto gold nanoparticles through S-Au and N-Au interactions, with the preeminence of a N10-like enol structure. The experiments also demonstrate that the synthesized TBA-coated gold nanoparticles can autoassociate by hydrogen bonding to form larger structures. This same H-bonding capacity also assures that these coated nanoparticles act as thistles toward proteins in solution, binding them strongly, presumably not by chemical reaction but by a network of hydrogen bonds.</text>
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                <text>&lt;strong&gt;M&amp;eacute;ndez, Eduardo&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Cerd&amp;aacute;, Mar&amp;iacute;a Fernanda&lt;/strong&gt;</text>
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                <text>&lt;a title="Curr&amp;iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=fd97168d9e8b7d3f82474969b5b78453" target="_blank"&gt;&lt;strong&gt;Gancheff, Jorge S.&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;a title="Curr&amp;iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=b1b8a8c8b1a5835b874ac1994003c38d" target="_blank"&gt;&lt;strong&gt;Torres, Julia&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;a title="Curr&amp;iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=6f16399c452f7b13f8a01a148cb38e12" target="_blank"&gt;&lt;strong&gt;Kremer, Carlos&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>&lt;strong&gt;Kieninger, Martina&lt;/strong&gt;</text>
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                <text>&lt;a title="Curr&amp;iacute;culum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=40f23b501897bd535c01b6602f1ea346" target="_blank"&gt;&lt;strong&gt;Ventura, Oscar N.&lt;/strong&gt;&lt;/a&gt;</text>
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            <name>Source</name>
            <description>A related resource from which the described resource is derived</description>
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              <elementText elementTextId="269642">
                <text>Journal of Physical Chemistry C v. 111, no. 8, 2007. -- p. 3369-3383</text>
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            <name>Publisher</name>
            <description>An entity responsible for making the resource available</description>
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              <elementText elementTextId="269643">
                <text>American Chemical Society</text>
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            <name>Date</name>
            <description>A point or period of time associated with an event in the lifecycle of the resource</description>
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              <elementText elementTextId="269644">
                <text>2007</text>
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          <element elementId="47">
            <name>Rights</name>
            <description>Information about rights held in and over the resource</description>
            <elementTextContainer>
              <elementText elementTextId="269645">
                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&lt;strong&gt;Tautomerism and reactivity in heterocyclic N-Oxides. A spectrocopic and theoretical study of benzimidazole N-Oxide derivatives (N-Hydroxybenzimidazoles.&lt;/strong&gt;</text>
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                <text>The tautomeric forms of benzimidazole N-oxide derivatives in solution were studied using nuclear magnetic resonance (NMR) techniques. Further insight into the molecular structures was provided by theoretical calculations using density functional theory (DFT). In the gas phase the N-hydroxy tautomer was more stable than the N-oxide, whereas in solution the stabilization of one form or the other depended on hydrogen bond formation involving the N-hydroxy/N-oxide moiety. Derivative 4 (n-butyl-5-nitrobenzimidazole-2-carboxamide 3-oxide), having a 2-carboxamide moiety, was the only compound studied present as a mixture of tautomers, the N-oxide being the predominant one. This was assigned to the formation of an internal hydrogen bond between the N-oxide group and the amide hydrogen atom. The tautomeric form present in the solid state was studied for derivative 1 (ethyl-5-nitrobenzimidazole-2-carboxylate 3-oxide) and was conclusively assigned by X-ray diffraction techniques to the N-hydroxy tautomer. In the crystal a strong O-H&amp;acirc;&amp;acirc;&amp;acirc;N intermolecular bond gives rise to supramolecular polymeric chains in the lattice. This strong interaction was also seen in the infrared spectrum and was assigned to two broad bands at 2367 and 2526 cm-1. The vibrational spectrum was satisfactorily described by DFT calculations and an example of this is the prediction of the band corresponding to the N-O stretching (N-oxide) just 1% lower than the experimental value. Uncorrelated calculations (HF) were not able to give an unambiguous assignment of this band. The reaction of derivative 1 against different kinds of electrophiles, hard and soft, led only to O-substituted products. This result was explained in terms of the HSAB theory using a local-global approach.</text>
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&lt;p&gt;(LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;&#13;
&lt;p&gt;&amp;nbsp;&lt;/p&gt;</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt;&amp;nbsp;La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>Se describen tres protocolos para la purificaci&amp;oacute;n, mediante cromatograf&amp;iacute;a de alta presi&amp;oacute;n (FPLC), de Tc45, un ant&amp;iacute;geno inmunogen&amp;eacute;ticamente definido de T. cruzi. Dos protocolos implicaron separaciones por tama&amp;ntilde;o molecular y uno por intercambio i&amp;oacute;nico. La presencia de Tc45 en las fracciones obtenidas fue monitoreada con sueros anti T. cruzi generados en dos cepas cong&amp;eacute;nitas de ratones (A.SW/A.CA) y en conejos. Aunque en las tres cromatograf&amp;iacute;as se lograron grados importantes de purificaci&amp;oacute;n, el intercambio i&amp;oacute;nico dio los mejores resultados, al entregar una fracci&amp;oacute;n que present&amp;oacute; una sola banda en inmunoelectrotransferencia, monitoreada con un suero de conejo poliespec&amp;iacute;fico. La metodolog&amp;iacute;a descrita tiene potencial para ser escalada y generar cantidades adecuadas de Tc45 para ser usado en ensayos de protecci&amp;oacute;n activa, secuenciaci&amp;oacute;n y obtenci&amp;oacute;n de anticuerpos monoclonales (AU)</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;&lt;strong&gt; ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones&lt;/p&gt;</text>
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                <text>The electronic spectra of triple-stranded complexes of Ti(IV) with bis(benzene-o-dithiolato) ligands (H4-L1 = 1,2-bis(2,3-dimercaptobenzamido)ethane; H4-L2 = 1,2-bis(2,3-dimercaptobenzamido)benzene) were investigated at the TD-DFT level of theory employing B3LYP/LANL2DZ. The influence of the nature (aliphatic or aromatic) of the spacer bridging both {Ti(S2C6H3)3} units on the absorptive features of the dinuclear complexes was also studied. B3LYP/LANL2DZ leads to spectra accounting for four absorption bands. At the lowest-energy region, the most important transitions are due to ligand-to-metal charge transfer (LMCT), in which out-of-plane ligand-centered orbitals and titanium-based MOs are involved. In going to the blue-region, a third band was detected with excitations showing an important contribution from ligand-to-ligand charge transfer (LLCT) and indeed, a combined LMCT+ LLCT character has been considered. This observation seems to arise from a decrease in the metallic character of the LUMOderivatives involved in the excitations. The origin of the absorption band at the highest-energy part of the spectrum is assigned to a LLCT. The influence of the nature of the spacer on the molar absorption coefficients (&amp;epsilon;) for this band has been clearly observed. The complex bearing aliphatic spacer shows &amp;epsilon; of about 5 E+4M&amp;minus;1 cm&amp;minus;1, while the one containing an aromatic spacer present a value of &amp;epsilon; of about 2 E+5M&amp;minus;1 cm&amp;minus;1.</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora&lt;/p&gt;</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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