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                <text>&lt;strong&gt;Microporus activated carbon fiber felt from Brazilian textile PAN fiber : preparation, characterization and application as super capacitor electrode&lt;/strong&gt;</text>
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                <text>Activated carbon fibers (ACF) are known as excellent adsorbent materials due to their fast adsorption rate and easy handling characteristic. The ACF can be manufactured from the polyacrylonitrile fiber, based on an usual carbon fibers (CF) production process accomplished by an additional activation process. The aim of the present work is to describe the production, chemical/morphological characterization and application potentiality of activated carbon fiber felt (ACFF) produced from textile PAN fiber, using a set of homemade equipment. The 5.0 dtex PAN fiber tow with 200 thousand filaments was oxidized and used as raw material for felt production. The oxidized PAN fiber felt (OPFF) was displaced in a special sample holder, carbonized (900 &amp;deg;C) and then activated in CO2 atmosphere at 1000 &amp;deg;C in an electric tubular furnace. All steps of the process were performed as fast as possible, and characterization was done by 77 K N2 isotherms, adsorption isotherms in liquid phase, scanning electronic microscope, X-ray diffraction and surface chemistry by Bhoem methodology. The results confirmed the production of essentially microporous (pore &amp;lt; 3.2 nm, centered on 1.2 nm) and 1,300 m2 g-1 surface area. The ACFF produced have demonstrated a strong potential application as electrode superc</text>
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                <text>&lt;strong&gt;Marcuzzo, Jossano S.&lt;/strong&gt;</text>
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                <text>Revista Brasileira de Aplica&amp;ccedil;&amp;otilde;es de V&amp;aacute;cuo v. 35, no. 2, 2016. -- p. 58-63</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>DOI: http://dx.doi.org/10.17563/rbav.v35i2.1022</text>
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                <text>&lt;strong&gt;The effect of manganite nanoparticle addition on the low field magnetoresistance of polyaniline&lt;/strong&gt;</text>
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                <text>In this report, we studied the effect of the addition of manganite nanoparticles on the microstructure and magnetotransport properties of polyaniline polymers. We showed experimental results on the fractal dimension of the polyaniline&amp;ndash;manganite nanocomposites by means of small angle X-ray scattering measurements. A decrease in the number of polarons is observed for the composite with a concentration of 20% manganite nanoparticles. On the other hand, for the same concentration, the presence of a low magnetic field increases the number of polarons, in relation to an enhancement of the negative low field magnetoresistance (LFMR). This enhancement was observed for a critical amount of manganite nanoparticle addition in the whole temperature regime analyzed, as envisaged from the low magnetic field dependence in the polyaniline polaron formation observed using confocal Raman spectroscopy at room temperature.</text>
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                <text>Journal of Materials Chemistry C v. 3, 2015. -- p. 12040-12047</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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&lt;p style="margin-bottom: 0cm;"&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>Journal of Molecular Catalysis B: Enzymatic v. 49, no. 1-4, 2007. -- p. 8-11</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>The barrier for internal rotation around the OOCH3 bond in 2,3,5,6- tetrafluoroanisole was calculated using the density functional theory (DFT) and secondorder M&amp;oslash;ller&amp;ndash;Plesset (MP2) methods with Pople&amp;rsquo;s basis sets up to 6-311��G(3df,2p) and Jensen basis sets up to pc-3. The results are converged only if fairly large basis sets are used (at least 6-311��G(3df,2pd) or pc-2). Both the DFT and MP2 potential energy curves show internal structure. Two minima and three maxima are observed on the curves, arising from the interplay between lone-pair delocalization and changes in the hybridization around the oxygen atom, together with the attraction between the positively polarized hydrogens in the methyl group and the negatively polarized fluorine atom at the ortho position. These critical points are somehow ironed out by the addition of zero-point and thermal corrections to the energy curves. At this level, the MP2 method can describe reasonably well the previously determined single-well experimental rotational barrier, 2.7 � 2.0 kcal/mol at 298 K, while all DFT methods yield a much smaller result. As observed experimentally, the OOCH3 group is perpendicular to the aryl ring in the equilibrium structure, although two very close minima with an intermediate hump at 90&amp;deg; are still observable. The theoretical free energy barrier of rotation at the MP2(full)/pc-2 level is 2.0 � 1.0 kcal/mol, in reasonable agreement with the experimental determination.</text>
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                <text>International Journal of Quantum Chemistry v. 107, no. 2, 2007. -- p. 403-417</text>
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>Disulfide reduction of Kluyveromyces lactis and Aspergillus oryzae &amp;beta;-galactosidases and &amp;beta;-lactoglobulin was assessed. Reduction was performed using one of two thiol-containing agents: dithiothreitol (DTT) or thiopropyl-agarose with a high degree of substitution (1000 &amp;mu;mol of SH groups/g of dried gel). Both reductants allowed an increase of three- (for K. lactis &amp;beta;-galactosidase) and fourfold (for A. oryzae &amp;beta;-galactosidase) in the initial content of SH groups in the lactases. Nearly sevenfold fewer micromoles of SH groups per milligram of protein were needed to perform the reduction of K. lactis &amp;beta;-galactosidase with thiopropyl-agarose than for the same reduction with DTT. However, for A. oryzae &amp;beta;-galactosidase, nearly twice as many micromoles of SH groups per milligram of protein were needed with thiopropylagarose than with DTT. Disulfide bonds in &amp;beta;-lactoglobulin were not accessible to thiopropyl-agarose, since this reduction was only possible in the presence of 6 M urea. These results proved that highly substituted thiopropyl-agarose is as good a reducing agent as DTT, for the reduction of disulfide bonds in proteins. Moreover, excess reducing agent was very simply separated from the reduced protein by filtration, making it easier to control the reaction and providing reduced protein solutions free of reductant. All these advantages substantially cut down the time required and therefore the cost of the overall process.</text>
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                <text>This enzyme immobilization approach involves the formation of disulfide (&amp;minus;S&amp;ndash;S&amp;ndash;) bonds with the support. Thus, enzymes bearing exposed nonessential thiol (SH) groups can be immobilized onto thiol-reactive supports provided with reactive disulfides or disulfide oxides under mild conditions. The great potential advantage of this approach is the reversibility of the bonds formed between the activated solid phase and the thiol-enzyme, because the bound protein can be released with an excess of a low-molecular-weight thiol (e.g., dithiothreitol [DTT]). This is of particular interest when the enzyme degrades much faster than the adsorbent, which can be reloaded afterwards. The possibility of reusing the polymeric support after inactivation of the enzyme may be of interest for the practical use of immobilized enzymes in large-scale processes in industry, where their use has often been hampered by the high cost of the support material. Disulfide oxides (thiolsulfinate or thiolsulfonate groups) can be introduced onto a wide variety of support materials with different degrees of porosity and with different mechanical resistances. Procedures are given for the preparation of thiol-activated solid phases and the covalent attachment of thiol-enzymes to the support material via disulfide bonds. The possibility of reusing the polymeric support is also shown.</text>
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                <text>Magnetic studies on hexaiodrohenate (IV) salts of univalent cations. Spin canting and magnetic ordering in K-2 [Rel(6)]with T-c=24 K</text>
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                <text>The ionic salts of rhenium(IV) of formula (Cat)2[ReI6] with Cat ) Li+ (1), Na+ (2), K+ (3), Rb+ (4), Cs+ (5), NH4 + (6), and AsPh4 + (7) [AsPh4 + ) tetraphenylarsonium cation] have been synthesized, and the structures of two of them (namely, 3 and 6) were determined by single-crystal X-ray diffraction. 3 crystallizes in the monoclinic system, space group Pn, with a ) 7.815(1) &amp;Aring;, b ) 7.874(1) &amp;Aring;, c ) 11.335(1) &amp;Aring;, &amp;acirc; ) 90.38(1)&amp;deg;, and Z ) 2 whereas 6 crystallizes in the tetragonal system, space group P4/mnc, with a ) 7.881(1) &amp;Aring;, b ) 7.881(1) &amp;Aring;, c ) 11.474(2) &amp;Aring;, and Z ) 2. The structures of 3 and 6 are made up of discrete [ReI6]2- anions and K+ (3) or NH4 + (6) cations held together by electrostatic forces (3 and 6) and N-H&amp;acirc;&amp;acirc;&amp;acirc;I hydrogen bonds (6). The rhenium(IV) cation in 3 and 6 is surrounded by six iodide ligands in an octahedral environment with the Re-I bond lengths varying in a very narrow range [2.704(3)-2.738(3) and 2.716(1)-2.722(2) &amp;Aring; for 3 and 6, respectively]. The [ReI6]2- anions in 6 describe a tetragonally distorted body-centered cubic structure. In 3, the arrangement of these units is similar but more distorted. The different arrangement of the anions in 3 and 6 accounts for the centrosymmetric (6) and non-centrosymmetric (3) structures observed. The magnetic properties of 1-7 were investigated in the temperature range 2.0-300 K. The magnetic behavior of 7 is that of a magnetically diluted Re(IV) complex with a large value of the zero-field splitting of the ground level (j2Dj ) 49.8 cm-1) whereas those of 1, 2, and 4-6 are typical of antiferromagnetically coupled systems with susceptibility maxima at 28 (1), 27 (2), 21 (4), 16 (5), and 20 K (6). In the case of compound 3, its magnetic behavior in the high-temperature range is parallel to that observed in the parent salts but below 24 K it is a weak ferromagnet with a canting angle of ca. 1.2&amp;deg;.</text>
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                <text>&lt;strong&gt;De Munno, G.&lt;/strong&gt;</text>
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                <text>Inorganic Chemistry v. 42, no. 8, 2003. -- p. 2512-2518</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>DOI: 10.1021/ic020531j</text>
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                <text>Universidad Nacional de San Luis</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA &lt;/strong&gt;La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&lt;strong&gt;Interaction of myo-inositol hexakisphosphate with biogenic and synthetic polyamines&lt;/strong&gt;</text>
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                <text>QUIMICA INORGANICA</text>
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                <text>MYO-INOSITOL</text>
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                <text>BIBLIOGRAFIA NACIONAL QUIMICA</text>
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                <text>Within all the eukaryotic cells myo-inositol phosphates (InsPs) are an important group of biomolecules that are potentially related to signaling functions. The most abundant member of this family in nature is InsP6 (phytate, L(12-) in its fully deprotonated form). The complicated chemical behavior of this molecule demands a great effort to understand its function in the cell medium. In this work we follow our earlier studies on the interaction of InsP6 with metal cations by inclusion of polyamines (both biogenic and synthetic) as potential agents to produce stable adducts. The stability constants of InsP6-amine adducts and the relevant thermodynamic parameters &amp;Delta;G&amp;deg;, &amp;Delta;H&amp;deg;, and &amp;Delta;S&amp;deg; were determined at 37.0 &amp;deg;C and 0.15 M ionic strength by means of potentiometric titrations and isothermal titration calorimetry (ITC). The biogenic amines studied were 1,4-diaminobutane (putrescine, put), 1,5-diaminopentane (cadaverine, cad), N-(3-aminopropyl)-1,4-diaminobutane (spermidine, spd), N,N'-bis(3-aminopropyl)-1,4-diaminobutane (spermine, spm), and 1-(4-aminobutyl)guanidine (agmatine, agm), while the synthetic models of longer polyamines were 1,19-dimethyl-1,4,7,10,13,16,19-heptaazanonadecane (Me2hexaen), 1,22-dimethyl-1,4,7,10,13,16,19,22-octaazadocosane (Me2heptaen), 1,25-dimethyl-1,4,7,10,13,16,19,22,25-nonaazapentacosane (Me2octaen) and N,N'-bis(3-aminopropyl)-1,3-propanediamine (3,3,3-tet). With the aid of molecular modeling, we also studied the structural aspects of molecular recognition in operation. The final result is a balance between many parameters including charge of the species, flexibility of the amines, H-bonds in the adduct, and desolvation processes.</text>
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                <text>&lt;strong&gt;Giorgi, Claudia&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Bianchi, Antonio&lt;/strong&gt;</text>
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                <text>Organic and Biomolecular Chemistry v. 13, no. 27, 2015. -- p. 7500-7512</text>
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              <elementText elementTextId="343423">
                <text>Royal Society of Chemistry</text>
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                <text>Ingl&amp;eacute;s</text>
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                <text>DOI: 10.1039/C5OB00900F</text>
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                  <text>Bibliografía Nacional Química</text>
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                <text>&lt;strong&gt;Interactions of W(VI) and Mo(VI) Oxyanions with Metal Cations in Natural Waters&lt;/strong&gt;</text>
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                <text>The association of tungsten(VI) and molybdenum(VI) oxyanions with metal cations was investigated under conditions simulating those prevailing in most natural waters. Potentiometric titrations were carried out for the systems containing tungsten(VI) or molybdenum(VI) anions and metal cations. The selection includes the major metal cations and some other ions of high environmental relevance. At neutral and basic pH values, in the presence of the most abundant metal cations, ionic pair species such as [Ca(WO4)] or [Ca(MoO4)] are formed to high extents. For the acidic pH range, polyoxoanion associations with cations are also found but are only relevant for tungsten(VI) in the conditions of the natural aquatic systems. The present results provide the basis for studying W(VI) and Mo(VI) speciation in natural aquatic systems, on which the environmental fate, bioavailability and toxicity of the elements depend.</text>
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                <text>&lt;strong&gt;Tissot, Florencia&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Santos, Patricia&lt;/strong&gt;</text>
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                <text>&lt;strong&gt;Ferrari, Carolina&lt;/strong&gt;</text>
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                <text>&lt;a title="Curriculum Vitae" href="http://buscadores.anii.org.uy/buscador_sni/exportador/ExportarPdf?hash=6f16399c452f7b13f8a01a148cb38e12" target="_blank"&gt;&lt;strong&gt;Kremer, Carlos&lt;/strong&gt;&lt;/a&gt;</text>
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                <text>Journal of Solution Chemistry |g v.45, 2016. -- p.1598–1611</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>&lt;strong&gt;Monitoreo de la calidad de las aguas naturales como propuesta educativa : un ni&amp;ntilde;o, un investigador&lt;/strong&gt;</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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                <text>Chagas&amp;rsquo; disease, considered incurable, is a major third world parasitosis that affects millions of people in Latin America. Previous work has shown that ruthenium clotrimazole complexes are more active against Trypanosoma cruzi , causative agent of Chagas&amp;rsquo; disease, than the corresponding free ligand. In this work, the synthesis and characterization of a series of new Ru(II) complexes with different antitrypanosomal active compounds is presented. Complexes of general formulae [RuIICl2(dmso)2L], where dmso�/ dimethylsulfoxide and L�/5-nitro-2-furaldehyde semicarbazone (L1), N4-n-butyl-5-nitro-2-furaldehyde semicarbazone (L2) or 3- (5-nitrofuryl)acroleine semicarbazone (L3), were prepared in good yields by reaction of [RuIICl2(dmso)4] with L in ethanol or toluene solutions. Complexes were characterized by elemental analyses and electronic, FTIR, 1H and 13C NMR spectroscopies. Crystal and molecular structures of [RuCl2(dmso)2L1] and [RuCl2(dmso)2L2] were determined by X-ray diffraction methods. In both crystals the ruthenium metal atom is in a quite similar elongated octahedral environment, equatorially coordinated to the semicarbazone molecule, acting as a bidentate ligand through its azomethynic nitrogen and carbonylic oxygen atoms. The sixfold coordination is completed with the sulfur atoms of two dimethylsulfoxide ligands at cis positions and two chlorine ions at the axial positions. The proposed formula for L3 complex was supported by FTIR, NMR and theoretical studies. NOE�/NMR experiments allowed to assign L3 spatial distribution in the complex.</text>
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                <text>El potencial antioxidante de diversos extractos vegetales est&amp;aacute; siendo reconocido como ventajoso frente a los antioxidantes sint&amp;eacute;ticos de uso corriente. En el presente art&amp;iacute;culo, se comparan extractos de romero, carqueja, or&amp;eacute;gano y marcela, extra&amp;iacute;dos utilizando como solvente etanol o CO2 (di&amp;oacute;xido de carbono) supercr&amp;iacute;tico. Sus efectos sobre el aceite de girasol se midieron mediante la determinaci&amp;oacute;n de la estabilidad oxidativa empleando un equipo Rancimat a 100 &amp;ordm;C o por el m&amp;eacute;todo del DPPH (radical difenilpicrilhidrazilo). Los resultados demuestran que el extracto de romero, provoca un aumento considerable en la estabilidad oxidativa, comparable al del TBHQ. Los otros extractos mencionados, tambi&amp;eacute;n exhiben un aumento, aunque menores a los de romero.</text>
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                <text>Supercritical fluid extraction with carbon dioxide has been demonstrated to be an attractive method to apply to different processes involved in the food industry due to several advantages when it is compared with conventional organic solvents. Supercritical CO2 extracts from rosemary (Rosmarinus officinalis), boldo (Peumus boldus), cedron (Aloysia citrodora), congorosa (Maytenus ilicifolia), yerba mate (Ilex paraguariensis) and pitanga (Eugenia uniflora) were obtained at different extraction conditions; their antioxidant effect was studied and compared with that obtained by traditional solvent maceration methods and with that shown by different common synthetic antioxidants. Additionally, antibacterial activity of extracts from the different herbs obtained was determined against different microorganisms. Supercritical extracts from these herbs were efficient in stabilizing sunflower oil; thus, they could represent a valuable natural alternative to synthetic antioxidants. Herbal extracts prove to be a source of compounds with antibacterial activity, with promising applications in the control of microbial deterioration of food.</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt; La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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