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                <text>&lt;strong&gt;Combustion global kinetic analysis of a hydrochar obtained from grape pomace&lt;/strong&gt;</text>
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                <text>This research explores the hydrochar production from grape pomace via hydrothermal carbonization and the determination of the kinetic parameters of its combustion process. The hydrochar was obtained by hydrothermal carbonization at 220 ◦C for 240 min with self-generated pressure. The process indicated a mass yield of 65.21 %, and the hydrochar exhibited an HHV of 26.60 MJ/kg, showing its potential as an efficient biofuel. Thermokinetic analysis of hydrochar combustion was conducted using multiple complementary methods: isoconversional analysis, mathematical deconvolution, combined kinetic analysis of each step, and optimization of parameters through nonlinear regression. The findings indicate that the overall process starts at ~152 ◦C and involves three apparent overlapping steps. The apparent activation energies were 165, 122.9, and 185.6 kJ/mol, while the apparent ln</text>
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&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;
&lt;p&gt;&lt;strong&gt;La legislación uruguaya protege el derecho&lt;/strong&gt; de autor sobre toda creación literaria, científica o artística, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeción a lo establecido por el derecho común y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt; La consulta de este documento queda condicionada a la aceptación de las siguientes condiciones de uso: Este documento es únicamente para usos privados enmarcados en actividades de investigación y docencia. No se autoriza su reproducción con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilización o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;
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                <text>&lt;strong&gt;Combustion global kinetic model of an industrial hydrochar&lt;/strong&gt;</text>
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                <text>This research analyzes the thermal and kinetic behavior of the combustion of hydrochar obtained industrially from green waste biomass. The combustion kinetic analysis was studied using thermogravimetry and applying complementary methods such as Friedman&amp;rsquo;s isoconversional analysis, mathematical deconvolution, combined kinetic analysis, and optimization by nonlinear regression of the kinetic curves. The process involves two overlapping steps: the organic compounds devolatilization and the oxidation of fixed carbon. For steps 1 and 2, the apparent activation energies were 178.5 and 183.1 kJ mol&amp;minus; 1, while the apparent ln(A∕s&amp;minus;1) were 31.2 and 30.0, respectively. The truncated &amp;Scaron;est&amp;aacute;k&amp;ndash;Berggren model was used as a surrogate for distributed reactivity, resulting in n1 = 1.37 and m1 = &amp;minus;0.54 for step 1, and n2 = 3.31 and m2 = 0.496 for step 2. In step 1, the m &amp;lt; 0 serves as a surrogate for an activation energy distribution, while in step 2, the value of n &amp;gt; 1 would substitute a gamma distribution of frequency factors. Finally, the obtained kinetic model allows successful predictions of thermal programs outside the range of the analysis.</text>
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                <text>&lt;strong&gt;Resentera, Alexander C.&lt;/strong&gt;</text>
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&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
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&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt;&amp;nbsp;La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;&#13;
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                <text>Gas-phase kinetics of the overall reactions of &amp;bull; OH and &amp;bull; Cl radicals with dihydrofuran-3(2H)-one (oxolan-3-one) and dihydro-2-methyl-3(2H)-furanone (2MTHF-3-one) were studied at 298 K and atmospheric pressure. The rate coefficients were determined using the relative method in a 480 L multipass glass reactor coupled to an FT-IR detection system. The rate coefficients found for oxolan 3-one and 2MTHF-one with &amp;bull; OH radicals (k1 and k2) and with &amp;bull; Cl atoms (k3 and k4) at 298 K and atmospheric pressure (in cm3 molecule&amp;minus; 1 s &amp;minus; 1 ) were: k1 = (1.86 &amp;plusmn; 0.29) &amp;times; 10&amp;minus; 11, k2 = (2.64 &amp;plusmn; 0.47) &amp;times; 10&amp;minus; 11, k3= (1.15 &amp;plusmn; 0.28) &amp;times; 10 &amp;minus; 10, and k4 = (1.33 &amp;plusmn; 0.32) &amp;times; 10&amp;minus; 10, respectively. Reactivity trends were developed by comparison with other similar structures and Fukui indices employed to determine the reactivity of different sites on the ring. The singularity of the reaction with &amp;bull; OH was assessed by computational studies which showed the formation of several stable hydrogen bonded complexes, explaining the difference with the reaction with the &amp;bull; Cl atom. SAR estimations of the rate coefficients were calculated and compared to the experimental values.</text>
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                <text>Chemosphere, v.338, 2023. -- e139500</text>
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt;&lt;/p&gt;&#13;
&lt;p&gt;(Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho&lt;/strong&gt;&amp;nbsp;de autor sobre toda creaci&amp;oacute;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA -&lt;/strong&gt;&amp;nbsp;La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;</text>
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                <text>An alternative to mitigate the consumption of fossil fuels is the use of biomass as an energy source. In this sense, the rural sector in Latin America has great potential due to its multiple biomass sources. For this reason, this study aims to analyze potential technologies related to the production of energy from biomass and its application in the Latin American rural sector. To achieve this, four key processes are analyzed. First is biomass conditioning through solar dryers. Next are the thermochemical processes that allow for their transformation into biofuels, for which the pyrolysis and the hydrothermal methods were selected due to the flexibility of the products obtained. Subsequently, cogeneration is studied to produce electrical and thermal energy from biomass or its derivatives. Finally, to close the CO2 cycle, a balance of CO2 fixation in a forest plantation is presented as an example of carbon accumulated in biomass. The literature systematic review allowed us to determine that the technologies mentioned in this work have different degrees of implementation in the Latin American rural sector. However, they have great potential to be applied on a large scale in the region, making it possible to adapt energy production to climate change and improve the life quality of its inhabitants.</text>
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                  <text>Tesis de doctorado, maestría, trabajos de diploma y monografías técnicas</text>
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                  <text>Versiones electrónicas de las tesis de doctorado, maestría y trabajos de diploma de la Facultad de Química, Universidad de la República (UdelaR).&#13;
Incluye únicamente trabajos hasta el año 2023. Los trabajos posteriores se encuentran disponibles en el Repositorio Colibrí.</text>
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                  <text>Departamento de Documentación y Biblioteca</text>
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          <element elementId="50">
            <name>Title</name>
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                <text>&lt;strong&gt;Licuefacci&amp;oacute;n hidrot&amp;eacute;rmica de madera de eucalipto y pino paras la producci&amp;oacute;n de biocombustibles&lt;/strong&gt;</text>
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                <text> FISICOQUÍMICA</text>
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                <text>BIOCOMBUSTIBLES</text>
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                <text>ENERGIA RENOVABLE</text>
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                <text>EUCALIPTO</text>
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                <text>PINO</text>
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          <element elementId="87">
            <name>Abstract</name>
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                <text>El uso desmedido de fuentes de energ&amp;iacute;a f&amp;oacute;siles ha provocado desbalances en la composici&amp;oacute;n atmosf&amp;eacute;rica lo que ha causado un efecto invernadero alterando la temperatura del planeta. Esta problem&amp;aacute;tica ambiental, sumada al esperado incremento del precio de los combustibles f&amp;oacute;siles en el futuro pr&amp;oacute;ximo, plantea la necesidad de explorar nuevas fuentes de energ&amp;iacute;a y por consiguiente desarrollar las tecnolog&amp;iacute;as adecuadas para su producci&amp;oacute;n. Una alternativa para la producci&amp;oacute;n de energ&amp;iacute;a y combustibles es la biomasa. Sin embargo, suele tener un alto contenido de humedad y de grupos oxigenados en su estructura qu&amp;iacute;mica, lo que hace que su poder calor&amp;iacute;fico sea inferior al de los combustibles f&amp;oacute;siles y su estabilidad temporal escasa. El uso de tratamientos termoqu&amp;iacute;micos o biol&amp;oacute;gicos permite transformar la biomasa en biocombustibles con mayor poder calor&amp;iacute;fico inferior (PCI), mayor estabilidad temporaria y en algunos casos adecuarlos a los sistemas existentes utilizados para combustibles f&amp;oacute;siles. Uno de los tratamientos termoqu&amp;iacute;micos utilizados es el procesamiento hidrot&amp;eacute;rmico. En especial, la licuefacci&amp;oacute;n hidrot&amp;eacute;rmica (LHT) es un proceso termoqu&amp;iacute;mico que consiste en someter la biomasa a temperaturas entre 250-400 oC y alta presi&amp;oacute;n (10-25 MPa) durante tiempos de residencia cortos (0-60 min) en medio acuoso [1] produciendo biocombustibles s&amp;oacute;lidos, l&amp;iacute;quidos y gaseosos, conocidos como hydrochar, biocrudo y gas, respectivamente y una soluci&amp;oacute;n acuosa rica en compuestos org&amp;aacute;nicos disueltos. Al ser un proceso en medio acuoso permite el uso de biomasa h&amp;uacute;meda sin necesidad de una operaci&amp;oacute;n previa de secado evitando con esto p&amp;eacute;rdidas energ&amp;eacute;ticas. Por otro lado, la biomasa a utilizar para fabricaci&amp;oacute;n de biocombustibles debe ser abundante y cercana al lugar de transformaci&amp;oacute;n para evitar altos costes de transporte. En el caso de Uruguay se estima una producci&amp;oacute;n de residuos lignocelul&amp;oacute;sicos de 2.2 a 2.8 millones de m3 por a&amp;ntilde;o ( 1.5 a 2 millones de toneladas por a&amp;ntilde;o) [2] siendo el eucalipto y el pino las maderas m&amp;aacute;s producidas. Es por esta disponibilidad de biomasa que se decidi&amp;oacute; estudiar la producci&amp;oacute;n de biocombustibles mediante LHT utilizando estas dos maderas. 3 4 En este trabajo se estudi&amp;oacute; el efecto de las condiciones de reacci&amp;oacute;n en la distribuci&amp;oacute;n de los productos de la LHT de madera de pino y eucalipto, as&amp;iacute; como la influencia de dichas condiciones sobre el PCI de los productos. Para ello se estudi&amp;oacute; el efecto del tiempo de residencia, la temperatura, la relaci&amp;oacute;n soluci&amp;oacute;n acuosa:biomasa y el uso de carbonato de potasio y bicarbonato de potasio como catalizadores, as&amp;iacute; como un an&amp;aacute;lisis de la factibilidad energ&amp;eacute;tica del proceso. Se determin&amp;oacute; que los par&amp;aacute;metros de reacci&amp;oacute;n influyen en la distribuci&amp;oacute;n de productos, siendo los de mayor influencia la relaci&amp;oacute;n soluci&amp;oacute;n:biomasa a la cual se trabaja y el uso de los catalizadores. Se obtuvieron biocrudos e hydrochar con mayor PCI que la biomasa de partida debido a la disminuci&amp;oacute;n del contenido de ox&amp;iacute;geno en el material.&#13;
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                <text>&lt;strong&gt;Reyes Plascencia, Carmina&lt;/strong&gt;</text>
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            <name>Publisher</name>
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                <text>Montevideo: UdelaR, Facultad de Qu&amp;iacute;mica&#13;
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                <text>&lt;strong&gt;Tancredi, Nestor&lt;/strong&gt;(director de Tesis)&#13;
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                <text>&lt;p&gt;&lt;strong&gt;Informaci&amp;oacute;n sobre Derechos de Autor&lt;/strong&gt; (Por favor lea este aviso antes de abrir los documentos u objetos)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;La legislaci&amp;oacute;n uruguaya protege el derecho de autor sobre toda creaci&amp;oacute;&lt;/strong&gt;n literaria, cient&amp;iacute;fica o art&amp;iacute;stica, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeci&amp;oacute;n a lo establecido por el derecho com&amp;uacute;n y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006)&lt;/p&gt;&#13;
&lt;p&gt;&lt;strong&gt;ADVERTENCIA&lt;/strong&gt; - La consulta de este documento queda condicionada a la aceptaci&amp;oacute;n de las siguientes condiciones de uso: Este documento es &amp;uacute;nicamente para usos privados enmarcados en actividades de investigaci&amp;oacute;n y docencia. No se autoriza su reproducci&amp;oacute;n con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilizaci&amp;oacute;n o cita de partes debe indicarse el nombre de la persona autora.&lt;/p&gt;&#13;
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                <text>Papel</text>
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            <name>Type</name>
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                <text>Tesis</text>
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                <text> 541.1 REY</text>
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        <name>Biocombustibles</name>
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        <name>Energía renovable</name>
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        <name>Eucalipto</name>
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