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https://riquim.fq.edu.uy/files/original/815276df210e8b16ff2916469ee7859b.pdf
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https://riquim.fq.edu.uy/files/original/0e8478d87e733e73f36a66c03ac94180.jpg
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Omeka Image File
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Bit Depth
8
Channels
3
Height
174
Width
156
Dublin Core
The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/.
Title
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Bibliografía Nacional Química
Description
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Contiene la producción científica nacional de los profesionales químicos e investigadores, durante el período 1929 hasta la fecha.
Contributor
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Departamento de Documentación y Biblioteca
RIQUIM
Document
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Original Format
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Pdf
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Dublin Core
The Dublin Core metadata element set is common to all Omeka records, including items, files, and collections. For more information see, http://dublincore.org/documents/dces/.
Title
A name given to the resource
<strong>Synthesis and evaluation of new heteroaryl nitrones with spin trap properties.</strong>
Subject
The topic of the resource
COMPUTACION QUIMICA
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ESPECTROSCOPIA DE RESONANCIA ESPIN
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RADICALES LIBRES
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REACCIONES DE FENTON
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QUINOXALINAS
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TEORIA FUNCIONAL DE LA DENSIDAD
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BIBLIOGRAFIA NACIONAL QUIIMICA
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2020
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Abstract
A summary of the resource.
A new series of heteroaryl nitrones were synthesized and evaluated as free radical traps due to the results showed in our previous report. The physicochemical characterization of these new nitrones by electron spin resonance (ESR) demonstrated their high capability to trap and stabilize different atom centered free radicals generated by the Fenton reaction. Additionally, we intensely studied them in terms of their physicochemical properties. Kinetic studies, including the use of a method based on competition and the hydroxyl adduct decay, gave the corresponding rate constants and half-lives at the physiological pH of these newly synthesized nitrones. New nitrones derived from quinoxaline 1,4-dioxide heterocycles were more suitable than DMPO to trap hydroxyl free radicals with a half-life longer than two hours. We explain some of the results using computational chemistry through density functional theory (DFT).
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Creator
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<strong>Barriga González, Germán</strong>
<strong>Aliaga, C.</strong>
<strong>Chamorro, E.</strong>
<strong>Olea-Azar, C.</strong>
<strong>Norambuena, E.</strong>
<strong>Porcal, Williams</strong>
<strong>González, Mercedes</strong>
<strong>Cerecetto, Hugo</strong>
Source
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RSC Advances v.10, no. 66. -- 2020. p. 40127-40135
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Publisher
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Royal Society of Chemistry
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Date
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2020
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Rights
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<p><strong>Información sobre Derechos de Autor</strong> (Por favor lea este aviso antes de abrir los documentos u objetos)<strong> La legislación uruguaya protege el derecho de autor </strong>sobre toda creación literaria, científica o artística, tanto en lo que tiene que ver con sus derechos morales, como en lo referente a los derechos patrimoniales con sujeción a lo establecido por el derecho común y las siguientes leyes (LEY 9.739 DE 17 DE DICIEMBRE DE 1937 SOBRE PROPIEDAD LITERARIA Y ARTISTICA CON LAS MODIFICACIONES INTRODUCIDAS POR LA LEY DE DERECHO DE AUTOR Y DERECHOS CONEXOS No. 17.616 DE 10 DE ENERO DE 2003, LEY 17.805 DE 26 DE AGOSTO DE 2004, LEY 18.046 DE 24 DE OCTUBRE DE 2006 LEY 18.046 DE 24 DE OCTUBRE DE 2006) ADVERTENCIA - La consulta de este documento queda condicionada a la aceptación de las siguientes condiciones de uso: Este documento es únicamente para usos privados enmarcados en actividades de investigación y docencia. No se autoriza su reproducción con fines de lucro. Esta reserva de derechos afecta tanto los datos del documento como a sus contenidos. En la utilización o cita de partes debe indicarse el nombre de la persona autora.</p>
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Format
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Pdf
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Language
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Inglés
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Type
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Artículo
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Identifier
An unambiguous reference to the resource within a given context
DOI: 10.1039/d0ra07720h
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Computación química
Espectroscopía de resonancia Espin
Quinoxalinas
Radicales libres
Teoría funcional de la densidad